Incipient modulated phase in Sr$_{1-x}$Ca$_{x}$TiO$_3$
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arXiv
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| Main Authors: | , , , , , , , , , , |
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| Format: | Preprint |
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2026
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| _version_ | 1866908768897335296 |
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| author | Fauqué, Benoît Chaney, Daniel A. Bourges, Philippe Raymond, Stéphane Hiess, Arno Steffens, Paul Baptiste, Benoît Paolasini, Luigi Bosak, Alexeï Behnia, Kamran Tomioka, Yasuhide |
| author_facet | Fauqué, Benoît Chaney, Daniel A. Bourges, Philippe Raymond, Stéphane Hiess, Arno Steffens, Paul Baptiste, Benoît Paolasini, Luigi Bosak, Alexeï Behnia, Kamran Tomioka, Yasuhide |
| contents | Nanometer-scale modulations can spontaneously emerge in complex materials when multiple degrees of freedom interact. Here we demonstrate that ferroelectric Sr$_{1-x}$Ca$_x$TiO$_3$ lies in close proximity to an incipient structurally modulated phase. Using inelastic neutron and X-ray scattering, we show that upon cooling, dipolar fluctuations strongly couple to and soften the $c_{44}$ transverse acoustic mode. We identify the wavevector at which this softening is maximal, thereby defining the characteristic length scale of the modulation. Calcium substitution enhances both the amplitude and the wavevector of the softening by strengthening the ferroelectric and antiferrodistortive instabilities. Our results demonstrate that nonlinear flexoelectric phonon coupling tends to stabilize a modulated state that cooperates with, rather than competes against, the other lattice instabilities in SrTiO$_3$. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2601_10516 |
| institution | arXiv |
| publishDate | 2026 |
| record_format | arxiv |
| spellingShingle | Incipient modulated phase in Sr$_{1-x}$Ca$_{x}$TiO$_3$ Fauqué, Benoît Chaney, Daniel A. Bourges, Philippe Raymond, Stéphane Hiess, Arno Steffens, Paul Baptiste, Benoît Paolasini, Luigi Bosak, Alexeï Behnia, Kamran Tomioka, Yasuhide Materials Science Superconductivity Nanometer-scale modulations can spontaneously emerge in complex materials when multiple degrees of freedom interact. Here we demonstrate that ferroelectric Sr$_{1-x}$Ca$_x$TiO$_3$ lies in close proximity to an incipient structurally modulated phase. Using inelastic neutron and X-ray scattering, we show that upon cooling, dipolar fluctuations strongly couple to and soften the $c_{44}$ transverse acoustic mode. We identify the wavevector at which this softening is maximal, thereby defining the characteristic length scale of the modulation. Calcium substitution enhances both the amplitude and the wavevector of the softening by strengthening the ferroelectric and antiferrodistortive instabilities. Our results demonstrate that nonlinear flexoelectric phonon coupling tends to stabilize a modulated state that cooperates with, rather than competes against, the other lattice instabilities in SrTiO$_3$. |
| title | Incipient modulated phase in Sr$_{1-x}$Ca$_{x}$TiO$_3$ |
| topic | Materials Science Superconductivity |
| url | https://arxiv.org/abs/2601.10516 |