Irreversible Kinetics Emerges from Bayesian Inference over Admissible Histories

Fuente: arXiv
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Autor principal: Upadhyay, Manas V.
Formato: Preprint
Publicado: 2026
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author Upadhyay, Manas V.
author_facet Upadhyay, Manas V.
contents A probabilistic formulation of irreversible kinetics is introduced in which incrementally admissible histories are weighted by a Gibbs-type measure built from an energy-dissipation action and observation constraints, with Theta controlling epistemic uncertainty. This measure can be interpreted as a Bayesian posterior over histories. In the zero-uncertainty limit, it concentrates on maximum-a-posteriori (MAP) histories, recovering classical deterministic evolution by incremental minimization in the convex generalized-standard-material setting, while allowing multiple competing MAP histories for non-convex energies or temporally coupled constraints. This emergence is demonstrated across seven distinct forward-in-time examples and an inverse inference problem of unknown histories from sparse observations via a global constrained minimum-action principle.
format Preprint
id arxiv_https___arxiv_org_abs_2601_10763
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Irreversible Kinetics Emerges from Bayesian Inference over Admissible Histories
Upadhyay, Manas V.
Statistical Mechanics
Machine Learning
74A20, 74D10
A probabilistic formulation of irreversible kinetics is introduced in which incrementally admissible histories are weighted by a Gibbs-type measure built from an energy-dissipation action and observation constraints, with Theta controlling epistemic uncertainty. This measure can be interpreted as a Bayesian posterior over histories. In the zero-uncertainty limit, it concentrates on maximum-a-posteriori (MAP) histories, recovering classical deterministic evolution by incremental minimization in the convex generalized-standard-material setting, while allowing multiple competing MAP histories for non-convex energies or temporally coupled constraints. This emergence is demonstrated across seven distinct forward-in-time examples and an inverse inference problem of unknown histories from sparse observations via a global constrained minimum-action principle.
title Irreversible Kinetics Emerges from Bayesian Inference over Admissible Histories
topic Statistical Mechanics
Machine Learning
74A20, 74D10
url https://arxiv.org/abs/2601.10763