Combining laser ablation and Sol-Gel techniques for the synthesis of nanostructured organic-inorganic matrices

Fuente: arXiv
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Autori principali: Haro-Poniatowski, E., Guarín, C. A., Mendoza-Luna, L. G., Escobar-Alarcón, L., Hernández-Pozos, J. L., Vera-Robles, L. I., Castillo, P., Cabello, F., Toudert, J., Chacón-Sánchez, F., García-Pardo, M., Serna, R., Gonzalo, J., Solís, J.
Natura: Preprint
Pubblicazione: 2026
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author Haro-Poniatowski, E.
Guarín, C. A.
Mendoza-Luna, L. G.
Escobar-Alarcón, L.
Hernández-Pozos, J. L.
Vera-Robles, L. I.
Castillo, P.
Cabello, F.
Toudert, J.
Chacón-Sánchez, F.
García-Pardo, M.
Serna, R.
Gonzalo, J.
Solís, J.
author_facet Haro-Poniatowski, E.
Guarín, C. A.
Mendoza-Luna, L. G.
Escobar-Alarcón, L.
Hernández-Pozos, J. L.
Vera-Robles, L. I.
Castillo, P.
Cabello, F.
Toudert, J.
Chacón-Sánchez, F.
García-Pardo, M.
Serna, R.
Gonzalo, J.
Solís, J.
contents In this work we report a new and simple method that combines the pulsed laser ablation in liquids (PLAL) and the Sol-Gel techniques to obtain nanocomposite glasses and gelatins. Gold nanoparticles (Au-NPs) are generated by PLAL using the corresponding target. The target is submerged in a transparent liquid solution made previously with tetraetylorthosilicate (TEOS) adding diluted hydrochloric acid as catalyzer. In the case of gelatins commercial gelatin and tap water are used. The laser source is a Nd:YAG laser emitting at 1064 nm, with an energy of 100 mJ and 8 ns pulse duration at 10 Hz repetition rate focused on the target in a 2 mm diameter laser spot. The ablation time is 10 min for the glasses and gelatins. The Au-NPs are uniformly dispersed in the solution. After the ablation process the gels are sealed and stored at room temperature for several days. The samples are characterized by UV-Vis spectroscopy, HRTEM, ellipsometry and AFM microscopy, these measurements reveal optical transparency and a refractive index near 1.45 for the pure glass, whereas a colorful aspect, a refractive index of 1.42, and a small surface roughness of 1.92 nm for the glass containing Au-NPs. In the case of gelatins self-sustained flexible films are obtained.
format Preprint
id arxiv_https___arxiv_org_abs_2601_10889
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Combining laser ablation and Sol-Gel techniques for the synthesis of nanostructured organic-inorganic matrices
Haro-Poniatowski, E.
Guarín, C. A.
Mendoza-Luna, L. G.
Escobar-Alarcón, L.
Hernández-Pozos, J. L.
Vera-Robles, L. I.
Castillo, P.
Cabello, F.
Toudert, J.
Chacón-Sánchez, F.
García-Pardo, M.
Serna, R.
Gonzalo, J.
Solís, J.
Mesoscale and Nanoscale Physics
Materials Science
In this work we report a new and simple method that combines the pulsed laser ablation in liquids (PLAL) and the Sol-Gel techniques to obtain nanocomposite glasses and gelatins. Gold nanoparticles (Au-NPs) are generated by PLAL using the corresponding target. The target is submerged in a transparent liquid solution made previously with tetraetylorthosilicate (TEOS) adding diluted hydrochloric acid as catalyzer. In the case of gelatins commercial gelatin and tap water are used. The laser source is a Nd:YAG laser emitting at 1064 nm, with an energy of 100 mJ and 8 ns pulse duration at 10 Hz repetition rate focused on the target in a 2 mm diameter laser spot. The ablation time is 10 min for the glasses and gelatins. The Au-NPs are uniformly dispersed in the solution. After the ablation process the gels are sealed and stored at room temperature for several days. The samples are characterized by UV-Vis spectroscopy, HRTEM, ellipsometry and AFM microscopy, these measurements reveal optical transparency and a refractive index near 1.45 for the pure glass, whereas a colorful aspect, a refractive index of 1.42, and a small surface roughness of 1.92 nm for the glass containing Au-NPs. In the case of gelatins self-sustained flexible films are obtained.
title Combining laser ablation and Sol-Gel techniques for the synthesis of nanostructured organic-inorganic matrices
topic Mesoscale and Nanoscale Physics
Materials Science
url https://arxiv.org/abs/2601.10889