A Landau-de Gennes Type Theory for Cholesteric-Helical Smectic-Smectic C* Liquid Crystal Phase Transitions

Fuente: arXiv
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Main Authors: Majumdar, Apala, Shi, Baoming, Wu, Dawei, Xia, Jingmin, Zhang, Lei
Format: Preprint
Published: 2026
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author Majumdar, Apala
Shi, Baoming
Wu, Dawei
Xia, Jingmin
Zhang, Lei
author_facet Majumdar, Apala
Shi, Baoming
Wu, Dawei
Xia, Jingmin
Zhang, Lei
contents We present a rigorous mathematical analysis of a modified Landau-de Gennes (LdG) theory modeling temperature-driven phase transitions between cholesteric, helical smectic, and smectic C* phases. This model couples a tensor-valued order parameter (nematic orientational order) with a real-valued order parameter (smectic layer modulation). We establish the existence of energy minimizers of the modified LdG energy in three dimensions, subject to Dirichlet conditions, and rigorously analyze the energy minimizers in two asymptotic limits. First, in the Oseen--Frank limit, we show that the global minimizer strongly converges to a minimizer of the Landau-de Gennes bulk energy. Second, in the limit of dominant elastic constants, we prove that the global minimizers converge to a classical helical director profile. Finally, through stability analysis and bifurcation theory, we derive the complete sequence of symmetry-breaking transitions with decreasing temperature-from the cholesteric phase (with in-plane twist and no layering) to an intermediate helical smectic phase (with in-plane twist and layering), and ultimately to the smectic C* phase (with out-of-plane twist and layering). These theoretical results are supported by numerical simulations.
format Preprint
id arxiv_https___arxiv_org_abs_2601_12653
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle A Landau-de Gennes Type Theory for Cholesteric-Helical Smectic-Smectic C* Liquid Crystal Phase Transitions
Majumdar, Apala
Shi, Baoming
Wu, Dawei
Xia, Jingmin
Zhang, Lei
Analysis of PDEs
We present a rigorous mathematical analysis of a modified Landau-de Gennes (LdG) theory modeling temperature-driven phase transitions between cholesteric, helical smectic, and smectic C* phases. This model couples a tensor-valued order parameter (nematic orientational order) with a real-valued order parameter (smectic layer modulation). We establish the existence of energy minimizers of the modified LdG energy in three dimensions, subject to Dirichlet conditions, and rigorously analyze the energy minimizers in two asymptotic limits. First, in the Oseen--Frank limit, we show that the global minimizer strongly converges to a minimizer of the Landau-de Gennes bulk energy. Second, in the limit of dominant elastic constants, we prove that the global minimizers converge to a classical helical director profile. Finally, through stability analysis and bifurcation theory, we derive the complete sequence of symmetry-breaking transitions with decreasing temperature-from the cholesteric phase (with in-plane twist and no layering) to an intermediate helical smectic phase (with in-plane twist and layering), and ultimately to the smectic C* phase (with out-of-plane twist and layering). These theoretical results are supported by numerical simulations.
title A Landau-de Gennes Type Theory for Cholesteric-Helical Smectic-Smectic C* Liquid Crystal Phase Transitions
topic Analysis of PDEs
url https://arxiv.org/abs/2601.12653