Rotating Magnetocaloric Effect in First-order Phase Transition Material Gd5Si2Ge2

Fuente: arXiv
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Main Authors: Almeida, Rafael, Kiefe, Rodrigo, Pinto, Ricardo Moura Costa, Amaral, João Sequeira, Dixon-Anderson, Kyle, Mudryk, Yaroslav, Araújo, João Pedro, Belo, João Horta
Format: Preprint
Published: 2026
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author Almeida, Rafael
Kiefe, Rodrigo
Pinto, Ricardo Moura Costa
Amaral, João Sequeira
Dixon-Anderson, Kyle
Mudryk, Yaroslav
Araújo, João Pedro
Belo, João Horta
author_facet Almeida, Rafael
Kiefe, Rodrigo
Pinto, Ricardo Moura Costa
Amaral, João Sequeira
Dixon-Anderson, Kyle
Mudryk, Yaroslav
Araújo, João Pedro
Belo, João Horta
contents The rotating magnetocaloric effect (RMCE) induced by self-demagnetization has been investigated in the giant magnetocaloric effect (GMCE) material Gd$_5$Si$_2$Ge$_2$. This shape-dependent effect had thus far only been reported in pure Gd, marking this as the first analysis of the effect in a sample with a magnetostructural first-order phase transition. By rotating the applied magnetic field vector while keeping its intensity constant, the demagnetizing field within a high-aspect ratio sample changes significantly, resulting in a RMCE. We characterize RMCE by determining the adiabatic temperature change ($ΔT_{ad}^{rot}$) directly through temperature measurements, and the isothermal entropy change ($ΔS_M^{rot}$) via magnetometry and magnetostatic simulations. We obtain a remarkable maximum $ΔT_{ad}^{rot}$ of 1.77 K for a constant external field of 0.8 T, higher than that obtained under 1.0 T. The magnetostatic simulations not only corroborate the highly non-monotonous field-dependence of $|ΔS_{M}^{rot}|$, which reaches 95\% of its maximum value at 0.8 T, 6.12 J K$^{-1}$ kg$^{-1}$ for the experimentally measured shape, but also estimate a 35\% increase in the maximum $|ΔS_{M}^{rot}|$ up to 8.67 J K$^{-1}$ kg$^{-1}$ in a simulated shape with higher aspect ratio.
format Preprint
id arxiv_https___arxiv_org_abs_2601_13239
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Rotating Magnetocaloric Effect in First-order Phase Transition Material Gd5Si2Ge2
Almeida, Rafael
Kiefe, Rodrigo
Pinto, Ricardo Moura Costa
Amaral, João Sequeira
Dixon-Anderson, Kyle
Mudryk, Yaroslav
Araújo, João Pedro
Belo, João Horta
Materials Science
Applied Physics
The rotating magnetocaloric effect (RMCE) induced by self-demagnetization has been investigated in the giant magnetocaloric effect (GMCE) material Gd$_5$Si$_2$Ge$_2$. This shape-dependent effect had thus far only been reported in pure Gd, marking this as the first analysis of the effect in a sample with a magnetostructural first-order phase transition. By rotating the applied magnetic field vector while keeping its intensity constant, the demagnetizing field within a high-aspect ratio sample changes significantly, resulting in a RMCE. We characterize RMCE by determining the adiabatic temperature change ($ΔT_{ad}^{rot}$) directly through temperature measurements, and the isothermal entropy change ($ΔS_M^{rot}$) via magnetometry and magnetostatic simulations. We obtain a remarkable maximum $ΔT_{ad}^{rot}$ of 1.77 K for a constant external field of 0.8 T, higher than that obtained under 1.0 T. The magnetostatic simulations not only corroborate the highly non-monotonous field-dependence of $|ΔS_{M}^{rot}|$, which reaches 95\% of its maximum value at 0.8 T, 6.12 J K$^{-1}$ kg$^{-1}$ for the experimentally measured shape, but also estimate a 35\% increase in the maximum $|ΔS_{M}^{rot}|$ up to 8.67 J K$^{-1}$ kg$^{-1}$ in a simulated shape with higher aspect ratio.
title Rotating Magnetocaloric Effect in First-order Phase Transition Material Gd5Si2Ge2
topic Materials Science
Applied Physics
url https://arxiv.org/abs/2601.13239