Alkali recondensation into chondrules

Fuente: arXiv
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Main Authors: Jacquet, Emmanuel, Marrocchi, Yves, Charnoz, Sébastien
Format: Preprint
Published: 2026
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author Jacquet, Emmanuel
Marrocchi, Yves
Charnoz, Sébastien
author_facet Jacquet, Emmanuel
Marrocchi, Yves
Charnoz, Sébastien
contents While sub-mm melt droplets should rapidly lose alkali elements in a vacuum at liquidus temperatures, chondrules are only modestly depleted in them (by less than one order of magnitude). The detection of sodium in olivine cores has previously suggested very high saturating partial pressures of gaseous sodium, but we show that alkalis were lost during heating and recondensed at lower temperatures, essentially in the present-day chondrule mesostases. This recondensation was accompanied by mass-dependent enrichment in light isotopes (for multi-isotope alkalis such as K and Rb), but its limited extent indicates a cooling acceleration (or "quenching"). The isotopic fractionation also constrains the ratio of the chondrule density and the cooling rate prior to the quench around $10^{-6}\:\mathrm{kg.m^{-3}.K^{-1}.h}$ suggesting densities above $\sim 10^{-6}\:\mathrm{kg/m^3}$. In a nebular context, this is achievable by radial and vertical concentrations near pressure bumps.
format Preprint
id arxiv_https___arxiv_org_abs_2601_15190
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Alkali recondensation into chondrules
Jacquet, Emmanuel
Marrocchi, Yves
Charnoz, Sébastien
Earth and Planetary Astrophysics
While sub-mm melt droplets should rapidly lose alkali elements in a vacuum at liquidus temperatures, chondrules are only modestly depleted in them (by less than one order of magnitude). The detection of sodium in olivine cores has previously suggested very high saturating partial pressures of gaseous sodium, but we show that alkalis were lost during heating and recondensed at lower temperatures, essentially in the present-day chondrule mesostases. This recondensation was accompanied by mass-dependent enrichment in light isotopes (for multi-isotope alkalis such as K and Rb), but its limited extent indicates a cooling acceleration (or "quenching"). The isotopic fractionation also constrains the ratio of the chondrule density and the cooling rate prior to the quench around $10^{-6}\:\mathrm{kg.m^{-3}.K^{-1}.h}$ suggesting densities above $\sim 10^{-6}\:\mathrm{kg/m^3}$. In a nebular context, this is achievable by radial and vertical concentrations near pressure bumps.
title Alkali recondensation into chondrules
topic Earth and Planetary Astrophysics
url https://arxiv.org/abs/2601.15190