The ALMA-ATOMS survey: Methanol emission in a large sample of hot molecular cores

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Main Authors: Zou, Jiahang, Liu, Tie, Qin, Sheng-Li, Peng, Yaping, Xu, Fengwei, Liu, Xunchuan, Chen, Li, Tang, Xindi, Dib, Sami, Li, Zi-Yang, Liu, Hong-Li, Juvela, Mika, Sanhueza, Patricio, Garcia, Pablo, Lee, Chang Won, Garay, Guido, Das, Swagat R., Zhang, Yan-Kun, Kim, Kee-Tae, Lee, Jeong-Eun, Liu, Meizhu, Bronfman, Leonardo, Kou, Zihping, Yang, Dongting, Wu, Gang, Hwang, Jihye, Meng, Dezhao, Tang, Mengyao, Chibueze, James O.
Format: Preprint
Published: 2026
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author Zou, Jiahang
Liu, Tie
Qin, Sheng-Li
Peng, Yaping
Xu, Fengwei
Liu, Xunchuan
Chen, Li
Tang, Xindi
Dib, Sami
Li, Zi-Yang
Liu, Hong-Li
Juvela, Mika
Sanhueza, Patricio
Garcia, Pablo
Lee, Chang Won
Garay, Guido
Das, Swagat R.
Zhang, Yan-Kun
Kim, Kee-Tae
Lee, Jeong-Eun
Liu, Meizhu
Bronfman, Leonardo
Kou, Zihping
Yang, Dongting
Wu, Gang
Hwang, Jihye
Meng, Dezhao
Tang, Mengyao
Chibueze, James O.
author_facet Zou, Jiahang
Liu, Tie
Qin, Sheng-Li
Peng, Yaping
Xu, Fengwei
Liu, Xunchuan
Chen, Li
Tang, Xindi
Dib, Sami
Li, Zi-Yang
Liu, Hong-Li
Juvela, Mika
Sanhueza, Patricio
Garcia, Pablo
Lee, Chang Won
Garay, Guido
Das, Swagat R.
Zhang, Yan-Kun
Kim, Kee-Tae
Lee, Jeong-Eun
Liu, Meizhu
Bronfman, Leonardo
Kou, Zihping
Yang, Dongting
Wu, Gang
Hwang, Jihye
Meng, Dezhao
Tang, Mengyao
Chibueze, James O.
contents Methanol (CH$_{3}$OH) is a key complex organic molecule (COM) in the interstellar medium, widely used as a tracer of dense gas and hot molecular cores (HMCs). Using high-resolution ALMA observations from the ATOMS survey, we investigate the excitation and abundance of methanol nuclear spin isomers and their relationship to chemical complexity in massive star-forming cores. We identify 20 methanol transitions, including A- and E-type lines in the v=0 state and E-type lines in the v$_{t}$=1 state, and detect 94 HMC candidates. Rotational temperature analysis under the LTE assumption yields average values of 194 $\pm$ 33 K for CH$_{3}$OH-E v$_{t}$=1, 178 $\pm$ 33 K for CH$_{3}$OH-A v=0, and 75 $\pm$ 33K for CH$_{3}$OH-E v=0. Emission from COMs other than methanol is detected in 87 of the 94 cores, with the CH$_{3}$OH-E v$_{t}$=1 line intensity showing a strong correlation with the channel detection ratio (CDR). These results demonstrate that CH$_{3}$OH-E v$_{t}$=1 lines are reliable tracers of HMCs and chemical complexity, and that the CDR provides a robust indicator of molecular richness. The temperature difference between A- and E-type methanol transitions is driven by anomalously strong J(2,J-2)$-$J(-1,J-1) lines, highlighting the importance of analyzing methanol symmetry types separately.
format Preprint
id arxiv_https___arxiv_org_abs_2601_18628
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle The ALMA-ATOMS survey: Methanol emission in a large sample of hot molecular cores
Zou, Jiahang
Liu, Tie
Qin, Sheng-Li
Peng, Yaping
Xu, Fengwei
Liu, Xunchuan
Chen, Li
Tang, Xindi
Dib, Sami
Li, Zi-Yang
Liu, Hong-Li
Juvela, Mika
Sanhueza, Patricio
Garcia, Pablo
Lee, Chang Won
Garay, Guido
Das, Swagat R.
Zhang, Yan-Kun
Kim, Kee-Tae
Lee, Jeong-Eun
Liu, Meizhu
Bronfman, Leonardo
Kou, Zihping
Yang, Dongting
Wu, Gang
Hwang, Jihye
Meng, Dezhao
Tang, Mengyao
Chibueze, James O.
Astrophysics of Galaxies
Methanol (CH$_{3}$OH) is a key complex organic molecule (COM) in the interstellar medium, widely used as a tracer of dense gas and hot molecular cores (HMCs). Using high-resolution ALMA observations from the ATOMS survey, we investigate the excitation and abundance of methanol nuclear spin isomers and their relationship to chemical complexity in massive star-forming cores. We identify 20 methanol transitions, including A- and E-type lines in the v=0 state and E-type lines in the v$_{t}$=1 state, and detect 94 HMC candidates. Rotational temperature analysis under the LTE assumption yields average values of 194 $\pm$ 33 K for CH$_{3}$OH-E v$_{t}$=1, 178 $\pm$ 33 K for CH$_{3}$OH-A v=0, and 75 $\pm$ 33K for CH$_{3}$OH-E v=0. Emission from COMs other than methanol is detected in 87 of the 94 cores, with the CH$_{3}$OH-E v$_{t}$=1 line intensity showing a strong correlation with the channel detection ratio (CDR). These results demonstrate that CH$_{3}$OH-E v$_{t}$=1 lines are reliable tracers of HMCs and chemical complexity, and that the CDR provides a robust indicator of molecular richness. The temperature difference between A- and E-type methanol transitions is driven by anomalously strong J(2,J-2)$-$J(-1,J-1) lines, highlighting the importance of analyzing methanol symmetry types separately.
title The ALMA-ATOMS survey: Methanol emission in a large sample of hot molecular cores
topic Astrophysics of Galaxies
url https://arxiv.org/abs/2601.18628