Is gelation a singularity or a flow induced instability?

Fuente: arXiv
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Autori principali: Dedola, Manuel, Cademartiri, Ludovico
Natura: Preprint
Pubblicazione: 2026
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author Dedola, Manuel
Cademartiri, Ludovico
author_facet Dedola, Manuel
Cademartiri, Ludovico
contents Gelation in the Smoluchowski coagulation equation is commonly interpreted as a finite-time singularity marked by mass loss or moment divergence. We instead characterize gelation as a loss of dynamical stability of the Smoluchowski flow, quantified through the time-dependent spectrum of the Jacobian along the evolving aggregation dynamics. Studying homogeneous kernels $K(i,j)=(ij)^α$ together with the classical Smoluchowski, we show that gelation is consistently preceded by the appearance of positive real eigenvalues, indicating a loss of local dynamical stability. While non-gelling kernels exhibit only transient finite-size effects, gelling kernels display persistent spectral destabilization associated with macroscopic gel formation. Our results identify gelation as a genuine dynamical instability of the Smoluchowski flow.
format Preprint
id arxiv_https___arxiv_org_abs_2601_18806
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Is gelation a singularity or a flow induced instability?
Dedola, Manuel
Cademartiri, Ludovico
Soft Condensed Matter
Adaptation and Self-Organizing Systems
Applications
Gelation in the Smoluchowski coagulation equation is commonly interpreted as a finite-time singularity marked by mass loss or moment divergence. We instead characterize gelation as a loss of dynamical stability of the Smoluchowski flow, quantified through the time-dependent spectrum of the Jacobian along the evolving aggregation dynamics. Studying homogeneous kernels $K(i,j)=(ij)^α$ together with the classical Smoluchowski, we show that gelation is consistently preceded by the appearance of positive real eigenvalues, indicating a loss of local dynamical stability. While non-gelling kernels exhibit only transient finite-size effects, gelling kernels display persistent spectral destabilization associated with macroscopic gel formation. Our results identify gelation as a genuine dynamical instability of the Smoluchowski flow.
title Is gelation a singularity or a flow induced instability?
topic Soft Condensed Matter
Adaptation and Self-Organizing Systems
Applications
url https://arxiv.org/abs/2601.18806