Spin-orbit coupling and beyond in Chiral-Induced Spin Selectivity

Fuente: arXiv
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Main Authors: Sala, Ruggero, Behera, Sushant Kumar, Karmakar, Abhirup Roy, Moioli, Matteo, Martinazzo, Rocco, Cococcioni, Matteo
Format: Preprint
Published: 2026
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_version_ 1866918418711576576
author Sala, Ruggero
Behera, Sushant Kumar
Karmakar, Abhirup Roy
Moioli, Matteo
Martinazzo, Rocco
Cococcioni, Matteo
author_facet Sala, Ruggero
Behera, Sushant Kumar
Karmakar, Abhirup Roy
Moioli, Matteo
Martinazzo, Rocco
Cococcioni, Matteo
contents Chiral-Induced Spin Selectivity (CISS) describes the emergence of spin-polarized electron transport in chiral systems without magnetic fields, a remarkable effect in light-element materials with weak intrinsic spin-orbit coupling (SOC). This mini-review analyzes the microscopic origins of CISS, highlighting how molecular chirality, local electric fields, and dynamic distortions enhance effective SOC and drive spin-dependent transport. We critically assess existing models in terms of their symmetry constraints, phenomenological assumptions, and compliance with Onsager reciprocity. Recent developments combining relativistic quantum mechanics and complete multipole representations reveal a direct link between chirality density and spin current pseudoscalars, suggesting a field-theoretic foundation for CISS. These insights could help position light-element chiral nanomaterials as tunable platforms for probing and engineering spin-selective phenomena at the nanoscale.
format Preprint
id arxiv_https___arxiv_org_abs_2601_20475
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Spin-orbit coupling and beyond in Chiral-Induced Spin Selectivity
Sala, Ruggero
Behera, Sushant Kumar
Karmakar, Abhirup Roy
Moioli, Matteo
Martinazzo, Rocco
Cococcioni, Matteo
Other Condensed Matter
Chiral-Induced Spin Selectivity (CISS) describes the emergence of spin-polarized electron transport in chiral systems without magnetic fields, a remarkable effect in light-element materials with weak intrinsic spin-orbit coupling (SOC). This mini-review analyzes the microscopic origins of CISS, highlighting how molecular chirality, local electric fields, and dynamic distortions enhance effective SOC and drive spin-dependent transport. We critically assess existing models in terms of their symmetry constraints, phenomenological assumptions, and compliance with Onsager reciprocity. Recent developments combining relativistic quantum mechanics and complete multipole representations reveal a direct link between chirality density and spin current pseudoscalars, suggesting a field-theoretic foundation for CISS. These insights could help position light-element chiral nanomaterials as tunable platforms for probing and engineering spin-selective phenomena at the nanoscale.
title Spin-orbit coupling and beyond in Chiral-Induced Spin Selectivity
topic Other Condensed Matter
url https://arxiv.org/abs/2601.20475