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Bibliographic Details
Main Authors: Chanan, Shivjeet, Kerchenfaut, Joseph, Illin, Eduard, Colla, Eugene V.
Format: Preprint
Published: 2026
Subjects:
Online Access:https://arxiv.org/abs/2601.21055
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Table of Contents:
  • The dynamical behavior of field-induced ferroelectric phase transitions in compositions of PbMg1/3Nb2/3O3(1-x)-PbTiO3(x) (PMN-PT) near the morphotropic phase boundary (MPB) was investigated using several electric-field application protocols. Our results show that PMN-PT compositions near the MPB exhibit phase-transition dynamics that differ markedly from those far below the MPB. We demonstrate that electric-field history significantly affects the field-induced transition temperature Tc, zero-field-cooling (ZFC) delay time tau_ZFC, and induced polarization Pc gained or lost during the transition. Furthermore, under specific field-temperature conditions, PMN-PT retains a memory of its electric-field history and uses it to kinetically accelerate ferroelectric ordering. We propose an explanation for the differences in phase-transition dynamics between MPB-proximal and MPB-distant compositions, contextualized within prior literature.