Defects, Corrugation and Temperature Govern Rarefied-Air Drag on Graphene Coatings

Fuente: arXiv
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Autori principali: Cajahuaringa, Samuel, Bidoggia, Davide, Peressi, Maria, Marrazzo, Antimo
Natura: Preprint
Pubblicazione: 2026
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author Cajahuaringa, Samuel
Bidoggia, Davide
Peressi, Maria
Marrazzo, Antimo
author_facet Cajahuaringa, Samuel
Bidoggia, Davide
Peressi, Maria
Marrazzo, Antimo
contents In rarefied atmospheric environments, where continuum fluid dynamics breaks down, aerodynamic drag is governed by gas-surface momentum exchange, making surface structure and chemistry key design knobs. Using molecular dynamics simulations, we show that coating the $α$-Al2O3(0001) surface with graphene markedly reduces the tangential momentum accommodation coefficient (TMAC) of N2, shifting scattering toward more specular reflection and thereby lowering drag; we further benchmark this response against graphite. The reduction strengthens up to 900 K. While structural defects can increase TMAC via defect-induced corrugation and local atomic and electronic rearrangements, graphene retains its performance at experimentally relevant defect densities.
format Preprint
id arxiv_https___arxiv_org_abs_2602_00285
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Defects, Corrugation and Temperature Govern Rarefied-Air Drag on Graphene Coatings
Cajahuaringa, Samuel
Bidoggia, Davide
Peressi, Maria
Marrazzo, Antimo
Materials Science
Chemical Physics
Fluid Dynamics
In rarefied atmospheric environments, where continuum fluid dynamics breaks down, aerodynamic drag is governed by gas-surface momentum exchange, making surface structure and chemistry key design knobs. Using molecular dynamics simulations, we show that coating the $α$-Al2O3(0001) surface with graphene markedly reduces the tangential momentum accommodation coefficient (TMAC) of N2, shifting scattering toward more specular reflection and thereby lowering drag; we further benchmark this response against graphite. The reduction strengthens up to 900 K. While structural defects can increase TMAC via defect-induced corrugation and local atomic and electronic rearrangements, graphene retains its performance at experimentally relevant defect densities.
title Defects, Corrugation and Temperature Govern Rarefied-Air Drag on Graphene Coatings
topic Materials Science
Chemical Physics
Fluid Dynamics
url https://arxiv.org/abs/2602.00285