Abundant hydrocarbons in a buried galactic nucleus with signs of carbonaceous grain and polycyclic aromatic hydrocarbon processing

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Auteurs principaux: García-Bernete, I., Pereira-Santaella, M., González-Alfonso, E., Agúndez, M., Rigopoulou, D., Donnan, F. R., Speranza, G., Thatte, N.
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Publié: 2026
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author García-Bernete, I.
Pereira-Santaella, M.
González-Alfonso, E.
Agúndez, M.
Rigopoulou, D.
Donnan, F. R.
Speranza, G.
Thatte, N.
author_facet García-Bernete, I.
Pereira-Santaella, M.
González-Alfonso, E.
Agúndez, M.
Rigopoulou, D.
Donnan, F. R.
Speranza, G.
Thatte, N.
contents Hydrocarbons play a key role in shaping the chemistry of the interstellar medium (ISM), but their enrichment and relationship with carbonaceous grains and polycyclic aromatic hydrocarbons (PAHs) still lack clear observational constraints. We report JWST NIRSpec+MIRI/MRS infrared (IR; 3-28 micron) observations of the local ultra-luminous IR galaxy (ULIRG) IRAS 07251-0248, revealing the extragalactic detection of small gas-phase hydrocarbons such as benzene (C$_6$H$_6$), triacetylene (C$_6$H$_2$), diacetylene (C$_4$H$_2$), acetylene (C$_2$H$_2$), methane (CH$_4$), and methyl radical (CH$_3$) as well as deep amorphous C-H absorptions in the solid phase. The unexpectedly high abundance of these molecules indicates an extremely rich hydrocarbon chemistry, not explained by high-temperature gas-phase chemistry, ice desorption or oxygen depletion. Instead, the most plausible explanation is the erosion and fragmentation of carbonaceous grains and PAHs. This scenario is supported by the correlation between the abundance of one of their main fragmentation products, C$_2$H$_2$, and cosmic ray (CR) ionization rate for a sample of local ULIRGs. These hydrocarbons are outflowing at $\sim$160 km/s, which may represent a potential formation pathway for hydrogenated amorphous grains. Our results suggest that IRAS 07251-0248 might not be unique but represents an extreme example of the commonly rich hydrocarbon chemistry prevalent in deeply obscured galactic nuclei.
format Preprint
id arxiv_https___arxiv_org_abs_2602_04967
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Abundant hydrocarbons in a buried galactic nucleus with signs of carbonaceous grain and polycyclic aromatic hydrocarbon processing
García-Bernete, I.
Pereira-Santaella, M.
González-Alfonso, E.
Agúndez, M.
Rigopoulou, D.
Donnan, F. R.
Speranza, G.
Thatte, N.
Astrophysics of Galaxies
Cosmology and Nongalactic Astrophysics
Solar and Stellar Astrophysics
Hydrocarbons play a key role in shaping the chemistry of the interstellar medium (ISM), but their enrichment and relationship with carbonaceous grains and polycyclic aromatic hydrocarbons (PAHs) still lack clear observational constraints. We report JWST NIRSpec+MIRI/MRS infrared (IR; 3-28 micron) observations of the local ultra-luminous IR galaxy (ULIRG) IRAS 07251-0248, revealing the extragalactic detection of small gas-phase hydrocarbons such as benzene (C$_6$H$_6$), triacetylene (C$_6$H$_2$), diacetylene (C$_4$H$_2$), acetylene (C$_2$H$_2$), methane (CH$_4$), and methyl radical (CH$_3$) as well as deep amorphous C-H absorptions in the solid phase. The unexpectedly high abundance of these molecules indicates an extremely rich hydrocarbon chemistry, not explained by high-temperature gas-phase chemistry, ice desorption or oxygen depletion. Instead, the most plausible explanation is the erosion and fragmentation of carbonaceous grains and PAHs. This scenario is supported by the correlation between the abundance of one of their main fragmentation products, C$_2$H$_2$, and cosmic ray (CR) ionization rate for a sample of local ULIRGs. These hydrocarbons are outflowing at $\sim$160 km/s, which may represent a potential formation pathway for hydrogenated amorphous grains. Our results suggest that IRAS 07251-0248 might not be unique but represents an extreme example of the commonly rich hydrocarbon chemistry prevalent in deeply obscured galactic nuclei.
title Abundant hydrocarbons in a buried galactic nucleus with signs of carbonaceous grain and polycyclic aromatic hydrocarbon processing
topic Astrophysics of Galaxies
Cosmology and Nongalactic Astrophysics
Solar and Stellar Astrophysics
url https://arxiv.org/abs/2602.04967