Saved in:
Bibliographic Details
Main Authors: Ferreira-Carvalho, M. M., Chen, S. H., Ku, Y. C., Jose, Anagha, Morrow, Ryan, Kuo, C. Y., Chang, C. F., Hu, Z., Haverkort, M. W., Tjeng, L. H.
Format: Preprint
Published: 2026
Subjects:
Online Access:https://arxiv.org/abs/2602.08361
Tags: Add Tag
No Tags, Be the first to tag this record!
Table of Contents:
  • We investigated the local Co 3d electronic structure of Na2BaCo(PO4)2 using polarization-dependent X-ray absorption spectroscopy (XAS) in combination with full multiplet cluster calculations. We employed the line-fitting inverse partial fluorescence yield (IPFY) technique to obtain accurate XAS spectra from strong insulating materials. Our combined experimental and theoretical analysis reveals a very small effective trigonal distortion of only 11 meV in the CoO6 octahedra, indicating a close to ideal condition to render a ground state with the Jeff = 1/2 character. With our cluster model we were also able to simulate magnetic susceptibility measurements along different directions in the crystal. These findings highlight Na2BaCo(PO4)2 as a promising platform for exploring exotic magnetic phenomena associated with Jeff = 1/2 ground states on triangular lattices.