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Main Authors: Lee, Dennis, Hensley, Brandon S., Chang, Tzu-Ching, Doré, Olivier
Format: Preprint
Published: 2026
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Online Access:https://arxiv.org/abs/2602.12331
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author Lee, Dennis
Hensley, Brandon S.
Chang, Tzu-Ching
Doré, Olivier
author_facet Lee, Dennis
Hensley, Brandon S.
Chang, Tzu-Ching
Doré, Olivier
contents Polycyclic aromatic hydrocarbons (PAHs) are responsible for a variety of near- and mid-infrared spectral features in Galactic and extragalactic sources. A feature at 1.05 $μ$m arising from electronic transitions in PAH cations is predicted by laboratory experiments but has never been observationally confirmed. We conduct a dedicated search for this feature in absorption on a highly-extinguished sight line toward BD+40 4223, a blue supergiant in Cyg OB2, using the TripleSpec spectrograph at Palomar Observatory. We place a $5σ$ upper limit on the feature strength of $Δτ_{1.05}/A_{V} < 5.6 \times10^{-3}$, ruling out theoretical estimates with $> 10σ$ significance. We constrain the effective temperature of BD+40 4223 to be $\log_{10}\left(T_{\rm eff}\right)=4.41\pm0.03$ and infer that it is veiled by $6.39\pm0.05$ magnitudes of visual extinction, consistent with but more constraining than previous determinations. As dust on the sight line toward BD+40 4223 appears typical of the diffuse interstellar medium, this non-detection challenges existing models of PAH material properties and/or charge distribution.
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institution arXiv
publishDate 2026
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spellingShingle Searching for the Shortest-wavelength Aromatic Infrared Bands: No Evidence for the Predicted 1.05 $μ$m Polycyclic Aromatic Hydrocarbon Feature
Lee, Dennis
Hensley, Brandon S.
Chang, Tzu-Ching
Doré, Olivier
Astrophysics of Galaxies
Polycyclic aromatic hydrocarbons (PAHs) are responsible for a variety of near- and mid-infrared spectral features in Galactic and extragalactic sources. A feature at 1.05 $μ$m arising from electronic transitions in PAH cations is predicted by laboratory experiments but has never been observationally confirmed. We conduct a dedicated search for this feature in absorption on a highly-extinguished sight line toward BD+40 4223, a blue supergiant in Cyg OB2, using the TripleSpec spectrograph at Palomar Observatory. We place a $5σ$ upper limit on the feature strength of $Δτ_{1.05}/A_{V} < 5.6 \times10^{-3}$, ruling out theoretical estimates with $> 10σ$ significance. We constrain the effective temperature of BD+40 4223 to be $\log_{10}\left(T_{\rm eff}\right)=4.41\pm0.03$ and infer that it is veiled by $6.39\pm0.05$ magnitudes of visual extinction, consistent with but more constraining than previous determinations. As dust on the sight line toward BD+40 4223 appears typical of the diffuse interstellar medium, this non-detection challenges existing models of PAH material properties and/or charge distribution.
title Searching for the Shortest-wavelength Aromatic Infrared Bands: No Evidence for the Predicted 1.05 $μ$m Polycyclic Aromatic Hydrocarbon Feature
topic Astrophysics of Galaxies
url https://arxiv.org/abs/2602.12331