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Auteurs principaux: Wieczerzak, Krzysztof, Cios, Grzegorz, Bała, Piotr, Michler, Johann, Jany, Benedykt R.
Format: Preprint
Publié: 2026
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Accès en ligne:https://arxiv.org/abs/2602.12848
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author Wieczerzak, Krzysztof
Cios, Grzegorz
Bała, Piotr
Michler, Johann
Jany, Benedykt R.
author_facet Wieczerzak, Krzysztof
Cios, Grzegorz
Bała, Piotr
Michler, Johann
Jany, Benedykt R.
contents Copper-silver (CuAg) alloys are increasingly explored for applications in high-performance electrical and electronic systems, owing to their unique combination of high electrical and thermal conductivity and enhanced mechanical strength. Nevertheless, a thorough understanding of how these alloys surface characteristics fundamentally influence properties remains largely underdeveloped. Here, we explored the complex interplay between surface texture morphology, layer composition, wetting, and optical properties of Cu, Ag, and CuAg thin films deposited on textured silicon substrates via magnetron sputtering. Employing data mining and machine learning techniques, we identified robust correlations between contact angle and surface fractal dimension across all layer types promoting Cassie-Baxter surface state formation. Our analysis revealed a significant connection between layer thickness and surface topography entropy deficit, suggesting a dynamic evolution of surface order/disorder during metal film growth. Furthermore, we observed that contact angle sensitivity to layer thickness implied a correlation with microstructure evolution. Through K-Means clustering, we successfully categorized the formed surface textures morphology. Finally, a Random Forest regression model was developed to accurately predict water contact angles (Mean Absolute Error around 5 deg) using only texture and optical parameters. The model, along with accompanying Python code, is publicly available. Our findings establish a pathway towards targeted surface texture morphology engineering for tailored material performance.
format Preprint
id arxiv_https___arxiv_org_abs_2602_12848
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Exploring Wetting and Optical Properties of CuAg Alloys via Surface Texture Morphology Analysis
Wieczerzak, Krzysztof
Cios, Grzegorz
Bała, Piotr
Michler, Johann
Jany, Benedykt R.
Materials Science
Copper-silver (CuAg) alloys are increasingly explored for applications in high-performance electrical and electronic systems, owing to their unique combination of high electrical and thermal conductivity and enhanced mechanical strength. Nevertheless, a thorough understanding of how these alloys surface characteristics fundamentally influence properties remains largely underdeveloped. Here, we explored the complex interplay between surface texture morphology, layer composition, wetting, and optical properties of Cu, Ag, and CuAg thin films deposited on textured silicon substrates via magnetron sputtering. Employing data mining and machine learning techniques, we identified robust correlations between contact angle and surface fractal dimension across all layer types promoting Cassie-Baxter surface state formation. Our analysis revealed a significant connection between layer thickness and surface topography entropy deficit, suggesting a dynamic evolution of surface order/disorder during metal film growth. Furthermore, we observed that contact angle sensitivity to layer thickness implied a correlation with microstructure evolution. Through K-Means clustering, we successfully categorized the formed surface textures morphology. Finally, a Random Forest regression model was developed to accurately predict water contact angles (Mean Absolute Error around 5 deg) using only texture and optical parameters. The model, along with accompanying Python code, is publicly available. Our findings establish a pathway towards targeted surface texture morphology engineering for tailored material performance.
title Exploring Wetting and Optical Properties of CuAg Alloys via Surface Texture Morphology Analysis
topic Materials Science
url https://arxiv.org/abs/2602.12848