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Bibliographic Details
Main Authors: del Rosso, Leonardo, Fortes, A. Dominic, Colognesi, Daniele, Santonocito, Alberto, Grazzi, Francesco, Berni, Selene, Celli, Milva
Format: Preprint
Published: 2026
Subjects:
Online Access:https://arxiv.org/abs/2602.13053
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Table of Contents:
  • The fundamental properties of ice have always attracted a lot of interest due to omnipresence of ice in many different natural contexts. Since cubic ice recently become experimentally accessible from a low-density gas hydrate precursor [1, 2], it has been possible to measure its density as a function of temperature in the whole thermodynamic range of metastability. We found strong analogies with respect to the other ice I polytype, i.e., hexagonal ice Ih [3], including the presence of a negative thermal expansion behavior at low temperature. Based on these results, a new enthalpy calculation quantifies the metastable nature of the cubic form and, consequently its inaccessibility from a "normal" ice Ih precursor.