Multielectron ionization in O$_2^+$ driven by intense infrared laser pulses

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Main Authors: Katsoulis, Georgios Petros, Emmanouilidou, Agapi
Format: Preprint
Published: 2026
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author Katsoulis, Georgios Petros
Emmanouilidou, Agapi
author_facet Katsoulis, Georgios Petros
Emmanouilidou, Agapi
contents We extend a recently developed three-dimensional semiclassical model [\href{https://journals.aps.org/pra/abstract/10.1103/PhysRevA.109.033106}{Phys. Rev. \textbf{A} 109, 033106 (2024)}] to study multielectron ionization and the formation of highly excited Rydberg states in O$_{2}^+$ driven by intense infrared laser pulses. Our model fully accounts for the Coulomb interaction between all particles, except for the Coulomb repulsion between bound electrons which is replaced by effective potentials. This replacement overcomes the hurdle of artificial autoinization. In addition, the multielectron motion is treated on an equal footing with nuclear motion, that is, electrons and nuclei are both allowed to move at the same time. We focus on triple and double ionization as well as frustrated triple and double ionization. For these processes, we identify and explain the main features of the sum of the kinetic energies of the final ion fragments resulting from the break-up of O$_{2}^+$. We also describe a physical mechanism that underlies frustrated triple ionization.
format Preprint
id arxiv_https___arxiv_org_abs_2602_14982
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Multielectron ionization in O$_2^+$ driven by intense infrared laser pulses
Katsoulis, Georgios Petros
Emmanouilidou, Agapi
Atomic Physics
We extend a recently developed three-dimensional semiclassical model [\href{https://journals.aps.org/pra/abstract/10.1103/PhysRevA.109.033106}{Phys. Rev. \textbf{A} 109, 033106 (2024)}] to study multielectron ionization and the formation of highly excited Rydberg states in O$_{2}^+$ driven by intense infrared laser pulses. Our model fully accounts for the Coulomb interaction between all particles, except for the Coulomb repulsion between bound electrons which is replaced by effective potentials. This replacement overcomes the hurdle of artificial autoinization. In addition, the multielectron motion is treated on an equal footing with nuclear motion, that is, electrons and nuclei are both allowed to move at the same time. We focus on triple and double ionization as well as frustrated triple and double ionization. For these processes, we identify and explain the main features of the sum of the kinetic energies of the final ion fragments resulting from the break-up of O$_{2}^+$. We also describe a physical mechanism that underlies frustrated triple ionization.
title Multielectron ionization in O$_2^+$ driven by intense infrared laser pulses
topic Atomic Physics
url https://arxiv.org/abs/2602.14982