Molecular diagnostics for the mid-infrared emission of planet-forming disks. Carbon and oxygen elemental abundances

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Autores principales: Arabhavi, Aditya M., Kamp, Inga, van Dishoeck, Ewine F., Woitke, Peter, Rab, Christian, Thi, Wing-Fai, Kaeufer, Till, Kanwar, Jayatee, Tabone, Benoît, Esteve, Pacôme, Vlasblom, Marissa
Formato: Preprint
Publicado: 2026
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author Arabhavi, Aditya M.
Kamp, Inga
van Dishoeck, Ewine F.
Woitke, Peter
Rab, Christian
Thi, Wing-Fai
Kaeufer, Till
Kanwar, Jayatee
Tabone, Benoît
Esteve, Pacôme
Vlasblom, Marissa
author_facet Arabhavi, Aditya M.
Kamp, Inga
van Dishoeck, Ewine F.
Woitke, Peter
Rab, Christian
Thi, Wing-Fai
Kaeufer, Till
Kanwar, Jayatee
Tabone, Benoît
Esteve, Pacôme
Vlasblom, Marissa
contents Mid-infrared observations of planet-forming disks reveal a wide diversity in molecular spectra. Carbon and oxygen abundances play a central role in setting the chemical environment of the inner disk and the spectral appearance. We aim to systematically explore how variations in elemental carbon and oxygen abundances affect the mid-infrared spectra of planet-forming disks, and to identify robust mid-infrared molecular diagnostics of C/H, O/H, and the C/O ratio. Using the thermochemical disk code ProDiMo and the line radiative transfer code FLiTs, we construct a grid of 25 models with varying carbon and oxygen abundances, covering a broad range of C/O ratios. We analyze the resulting mid-infrared molecular emission, including species such as $\rm H_2O$, $\rm CO$, $\rm CO_2$, $\rm C_2H_2$, $\rm OH$. We find that the mid-infrared molecular spectra are highly sensitive not only to the C/O ratio, but also to the absolute abundances of carbon and oxygen. Despite the same disk structure and C/O ratios, molecular fluxes (e.g., $\rm C_2H_2$, $\rm CO_2$) vary by more than an order of magnitude. This variation stems from the differences in excitation conditions and emitting regions caused by the elemental abundances of oxygen and carbon. We identify diagnostic molecular flux ratios - such as $\rm CO_2$/$\rm H_2O$ and $\rm H_2O$/$\rm C_2H_2$ - that can serve as tracers of C/H and O/H respectively. By combining these diagnostics, we demonstrate a method to infer the underlying C/O ratio. Our model grid provides a framework for interpreting mid-infrared molecular emission from disks, allowing estimates of elemental abundances if the disk properties and structure are known. Comparisons with recent JWST observations suggest that a variety in C and O abundances is seen in a sample of T Tauri disks, possibly shaped by disk transport processes and the presence of gaps.
format Preprint
id arxiv_https___arxiv_org_abs_2602_16030
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Molecular diagnostics for the mid-infrared emission of planet-forming disks. Carbon and oxygen elemental abundances
Arabhavi, Aditya M.
Kamp, Inga
van Dishoeck, Ewine F.
Woitke, Peter
Rab, Christian
Thi, Wing-Fai
Kaeufer, Till
Kanwar, Jayatee
Tabone, Benoît
Esteve, Pacôme
Vlasblom, Marissa
Earth and Planetary Astrophysics
Astrophysics of Galaxies
Solar and Stellar Astrophysics
Mid-infrared observations of planet-forming disks reveal a wide diversity in molecular spectra. Carbon and oxygen abundances play a central role in setting the chemical environment of the inner disk and the spectral appearance. We aim to systematically explore how variations in elemental carbon and oxygen abundances affect the mid-infrared spectra of planet-forming disks, and to identify robust mid-infrared molecular diagnostics of C/H, O/H, and the C/O ratio. Using the thermochemical disk code ProDiMo and the line radiative transfer code FLiTs, we construct a grid of 25 models with varying carbon and oxygen abundances, covering a broad range of C/O ratios. We analyze the resulting mid-infrared molecular emission, including species such as $\rm H_2O$, $\rm CO$, $\rm CO_2$, $\rm C_2H_2$, $\rm OH$. We find that the mid-infrared molecular spectra are highly sensitive not only to the C/O ratio, but also to the absolute abundances of carbon and oxygen. Despite the same disk structure and C/O ratios, molecular fluxes (e.g., $\rm C_2H_2$, $\rm CO_2$) vary by more than an order of magnitude. This variation stems from the differences in excitation conditions and emitting regions caused by the elemental abundances of oxygen and carbon. We identify diagnostic molecular flux ratios - such as $\rm CO_2$/$\rm H_2O$ and $\rm H_2O$/$\rm C_2H_2$ - that can serve as tracers of C/H and O/H respectively. By combining these diagnostics, we demonstrate a method to infer the underlying C/O ratio. Our model grid provides a framework for interpreting mid-infrared molecular emission from disks, allowing estimates of elemental abundances if the disk properties and structure are known. Comparisons with recent JWST observations suggest that a variety in C and O abundances is seen in a sample of T Tauri disks, possibly shaped by disk transport processes and the presence of gaps.
title Molecular diagnostics for the mid-infrared emission of planet-forming disks. Carbon and oxygen elemental abundances
topic Earth and Planetary Astrophysics
Astrophysics of Galaxies
Solar and Stellar Astrophysics
url https://arxiv.org/abs/2602.16030