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Bibliographic Details
Main Authors: Ebert, Adrian, Fromme, Simon, Burgert, Lisa, Rashid, Umar, Gerhard, Lukas, Feye, Julia, Kuppusamy, Senthil Kumar, Brachnakova, Barbora, Neumann, Timo, Ruben, Mario, Roesky, Peter W., Seitz, Michael, Wulfhekel, Wulf
Format: Preprint
Published: 2026
Subjects:
Online Access:https://arxiv.org/abs/2602.16377
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Table of Contents:
  • The application of rare-earth complexes in electrically driven light sources poses a series of challenges that require specific optimization of the molecular photophysical properties. Here, we present a report on films of three different Eu3+ complexes characterized in terms of emission spectra and fluorescence decay. We compare molecular complexes in powder form and sublimed films, in films on glass and on a metal surface, and in films of thicknesses down to less than 3 nm (< 3 ML), approaching electrical coupling. Our photoluminescence experiments supported by scanning tunneling microscopy of sub-monolayers indicate that Eu3+(trensal) complexes are less affected by sublimation and more stable on the metal surface than typical beta diketonate complexes, making them promising candidates for electroluminescence devices.