A kinetic interpretation of thermomechanical restrictions of continua

Fuente: arXiv
Guardado en:
Detalles Bibliográficos
Autores principales: Farrell, Patrick E., Málek, Josef, Souček, Ondřej, Zerbinati, Umberto
Formato: Preprint
Publicado: 2026
Materias:
Acceso en línea:
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
_version_ 1866917453808795648
author Farrell, Patrick E.
Málek, Josef
Souček, Ondřej
Zerbinati, Umberto
author_facet Farrell, Patrick E.
Málek, Josef
Souček, Ondřej
Zerbinati, Umberto
contents Rajagopal and Srinivasa's thermodynamic framework derives constitutive relations in continuum mechanics from two scalar functions describing energy storage and entropy production via a constrained optimization principle. In parallel, kinetic theory obtains constitutive laws through moment closure, most notably via the Chapman--Enskog expansion. This work has three objectives. First, we establish a connection between these approaches by providing a kinetic interpretation of the Rajagopal--Srinivasa principle of maximal entropy production, under appropriate albeit restrictive hypotheses. For a Bhatnagar--Gross--Krook-type approximation, we show that the Rajagopal--Srinivasa principle is equivalent to a minimal relaxation-time principle, selecting among admissible constitutive responses the one with the fastest compatible relaxation toward equilibrium. Second, we review the classical kinetic description of continua in a manner accessible to those familiar with continuum thermodynamics. Third, we propose a hybrid Chapman--Enskog--Rajagopal--Srinivasa approach which computes the thermodynamic relations and entropy production from the Chapman--Enskog expansion, and then invokes the Rajagopal--Srinivasa principle to determine the other constitutive relations. This recovers the standard Euler and Navier--Stokes--Fourier constitutive laws for monatomic gases. We also demonstrate how different choices of selection procedure can be more informative than the classical Chapman--Enskog closure in the context of an inviscid compressible Leslie--Ericksen model arising in liquid crystals.
format Preprint
id arxiv_https___arxiv_org_abs_2602_21384
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle A kinetic interpretation of thermomechanical restrictions of continua
Farrell, Patrick E.
Málek, Josef
Souček, Ondřej
Zerbinati, Umberto
Mathematical Physics
Rajagopal and Srinivasa's thermodynamic framework derives constitutive relations in continuum mechanics from two scalar functions describing energy storage and entropy production via a constrained optimization principle. In parallel, kinetic theory obtains constitutive laws through moment closure, most notably via the Chapman--Enskog expansion. This work has three objectives. First, we establish a connection between these approaches by providing a kinetic interpretation of the Rajagopal--Srinivasa principle of maximal entropy production, under appropriate albeit restrictive hypotheses. For a Bhatnagar--Gross--Krook-type approximation, we show that the Rajagopal--Srinivasa principle is equivalent to a minimal relaxation-time principle, selecting among admissible constitutive responses the one with the fastest compatible relaxation toward equilibrium. Second, we review the classical kinetic description of continua in a manner accessible to those familiar with continuum thermodynamics. Third, we propose a hybrid Chapman--Enskog--Rajagopal--Srinivasa approach which computes the thermodynamic relations and entropy production from the Chapman--Enskog expansion, and then invokes the Rajagopal--Srinivasa principle to determine the other constitutive relations. This recovers the standard Euler and Navier--Stokes--Fourier constitutive laws for monatomic gases. We also demonstrate how different choices of selection procedure can be more informative than the classical Chapman--Enskog closure in the context of an inviscid compressible Leslie--Ericksen model arising in liquid crystals.
title A kinetic interpretation of thermomechanical restrictions of continua
topic Mathematical Physics
url https://arxiv.org/abs/2602.21384