On-surface synthesis and aromaticity of large cyclocarbons
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| Main Authors: | , , , , , , , , , , , , , , |
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| Format: | Preprint |
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2026
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| author | Sellies, Lisanne Vitek, Marco Gao, Yueze Paschke, Fabian Albrecht, Florian Eckrich, Jakob Dempsey, Beren Barison, Stefano Lieske, Leonard-Alexander Piccinelli, Samuele Baiardi, Alberto Tavernelli, Ivano Anderson, Harry L. Rončević, Igor Gross, Leo |
| author_facet | Sellies, Lisanne Vitek, Marco Gao, Yueze Paschke, Fabian Albrecht, Florian Eckrich, Jakob Dempsey, Beren Barison, Stefano Lieske, Leonard-Alexander Piccinelli, Samuele Baiardi, Alberto Tavernelli, Ivano Anderson, Harry L. Rončević, Igor Gross, Leo |
| contents | Molecular rings of N carbon atoms, that is, cyclo[N]carbons, or C$_N$, can be formed by tip-induced chemistry [1-7]. Because of their monocyclic geometry, cyclocarbons are fundamentally important for testing theoretical models of aromaticity [8-11]. Here, we synthesized large cyclo[N]carbons, with N up to 88, by tip-induced chemistry on a NaCl surface and studied their aromaticity by measuring their transport gaps by scanning tunnelling spectroscopy. We first generated C$_{20}$ and C$_{22}$, and then fused multiple cyclocarbons [5-7] by means of atom manipulation, obtaining C$_{42}$, C$_{44}$, C$_{46}$, C$_{66}$ and C$_{88}$. In agreement with predictions obtained using a finely tuned density functional [12-15] and large active space approximate configuration interaction calculations executed on quantum hardware [16, 17], we observe a substantially smaller transport gap for C$_{20}$ (N = 4n) compared to C$_{22}$ (4n+2), and for C$_{44}$ (4n) relative to C$_{42}$ (4n+2). In larger cyclocarbons, the oscillation of the transport gap between anti-aromatic N = 4n and aromatic N = 4n+2 cyclocarbons becomes smaller, and is expected to eventually vanish with increasing N, indicating non-aromaticity. Our experimental results show that aromaticity persists at N = 42, and theory predicts ring currents comparable in magnitude to that of benzene in cyclocarbons of this size. In the future, such large cyclocarbons could be used to study conductance, quantum interference, and the effects of aromaticity in single atomic carbon wires and circuits. |
| format | Preprint |
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arxiv_https___arxiv_org_abs_2603_02040 |
| institution | arXiv |
| publishDate | 2026 |
| record_format | arxiv |
| spellingShingle | On-surface synthesis and aromaticity of large cyclocarbons Sellies, Lisanne Vitek, Marco Gao, Yueze Paschke, Fabian Albrecht, Florian Eckrich, Jakob Dempsey, Beren Barison, Stefano Lieske, Leonard-Alexander Piccinelli, Samuele Baiardi, Alberto Tavernelli, Ivano Anderson, Harry L. Rončević, Igor Gross, Leo Mesoscale and Nanoscale Physics Molecular rings of N carbon atoms, that is, cyclo[N]carbons, or C$_N$, can be formed by tip-induced chemistry [1-7]. Because of their monocyclic geometry, cyclocarbons are fundamentally important for testing theoretical models of aromaticity [8-11]. Here, we synthesized large cyclo[N]carbons, with N up to 88, by tip-induced chemistry on a NaCl surface and studied their aromaticity by measuring their transport gaps by scanning tunnelling spectroscopy. We first generated C$_{20}$ and C$_{22}$, and then fused multiple cyclocarbons [5-7] by means of atom manipulation, obtaining C$_{42}$, C$_{44}$, C$_{46}$, C$_{66}$ and C$_{88}$. In agreement with predictions obtained using a finely tuned density functional [12-15] and large active space approximate configuration interaction calculations executed on quantum hardware [16, 17], we observe a substantially smaller transport gap for C$_{20}$ (N = 4n) compared to C$_{22}$ (4n+2), and for C$_{44}$ (4n) relative to C$_{42}$ (4n+2). In larger cyclocarbons, the oscillation of the transport gap between anti-aromatic N = 4n and aromatic N = 4n+2 cyclocarbons becomes smaller, and is expected to eventually vanish with increasing N, indicating non-aromaticity. Our experimental results show that aromaticity persists at N = 42, and theory predicts ring currents comparable in magnitude to that of benzene in cyclocarbons of this size. In the future, such large cyclocarbons could be used to study conductance, quantum interference, and the effects of aromaticity in single atomic carbon wires and circuits. |
| title | On-surface synthesis and aromaticity of large cyclocarbons |
| topic | Mesoscale and Nanoscale Physics |
| url | https://arxiv.org/abs/2603.02040 |