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| Main Authors: | , , , |
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| Format: | Preprint |
| Published: |
2026
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| Subjects: | |
| Online Access: | https://arxiv.org/abs/2603.02466 |
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| _version_ | 1866910060482920448 |
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| author | Kim, Hyeon Woo Lee, Han Uk Mishra, Rohan Cho, Sung Beom |
| author_facet | Kim, Hyeon Woo Lee, Han Uk Mishra, Rohan Cho, Sung Beom |
| contents | Vapor deposition allows for the synthesis of metastable polymorphs with unique properties, yet polymorph selection remains largely empirical due to the lack of predictive guidelines bridging thermodynamics, kinetics, and synthesis conditions. Here, we show that precursor chemistry can control metastable polymorph selection by modulating the reaction driving force governing nucleation. By integrating first-principles reaction energetics and substrate interactions into classical nucleation theory, we establish a quantitative framework that connects precursor-dependent reaction energetics to polymorph accessibility during vapor deposition. Using Ga2O3 as a model system, we demonstrate that highly reactive precursors with large reaction driving forces kinetically stabilize the metastable α phase, whereas low-driving-force precursors permit thermodynamic relaxation to the stable \b{eta} phase. Furthermore, precursor flow rates amplify supersaturation, expanding the kinetic window for stabilizing the elusive \k{appa} phase. The predictive capability of this approach is further validated in the TiO2 system, where precursor-dependent reaction energetics correctly capture the competitive nucleation between rutile and anatase. These results establish precursor chemistry as a tunable chemical lever for controlling nucleation kinetics and provide a predictive design principle for metastable polymorph synthesis in vapor deposition. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2603_02466 |
| institution | arXiv |
| publishDate | 2026 |
| record_format | arxiv |
| spellingShingle | Precursor-Dependent Energetics as a Predictive Principle for Polymorph Selection in Thin Films Kim, Hyeon Woo Lee, Han Uk Mishra, Rohan Cho, Sung Beom Materials Science Vapor deposition allows for the synthesis of metastable polymorphs with unique properties, yet polymorph selection remains largely empirical due to the lack of predictive guidelines bridging thermodynamics, kinetics, and synthesis conditions. Here, we show that precursor chemistry can control metastable polymorph selection by modulating the reaction driving force governing nucleation. By integrating first-principles reaction energetics and substrate interactions into classical nucleation theory, we establish a quantitative framework that connects precursor-dependent reaction energetics to polymorph accessibility during vapor deposition. Using Ga2O3 as a model system, we demonstrate that highly reactive precursors with large reaction driving forces kinetically stabilize the metastable α phase, whereas low-driving-force precursors permit thermodynamic relaxation to the stable \b{eta} phase. Furthermore, precursor flow rates amplify supersaturation, expanding the kinetic window for stabilizing the elusive \k{appa} phase. The predictive capability of this approach is further validated in the TiO2 system, where precursor-dependent reaction energetics correctly capture the competitive nucleation between rutile and anatase. These results establish precursor chemistry as a tunable chemical lever for controlling nucleation kinetics and provide a predictive design principle for metastable polymorph synthesis in vapor deposition. |
| title | Precursor-Dependent Energetics as a Predictive Principle for Polymorph Selection in Thin Films |
| topic | Materials Science |
| url | https://arxiv.org/abs/2603.02466 |