The Statistical Mechanics of Indistinguishable Energy States and the Glass Transition

Fuente: arXiv
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Autor principal: Akhanjee, Shimul
Formato: Preprint
Publicado: 2026
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author Akhanjee, Shimul
author_facet Akhanjee, Shimul
contents The statistical mechanics of particles that populate indistinguishable energy sub-states is explored. In particular, the mathematical treatment of the microstates differs from conventional statistical mechanics where for a given degeneracy, the energy sub-levels or sub-states are universally treated as distinguishable, and differentiated by unique quantum numbers, or addressed by distinct spatial locations. Results from combinatorial counting problems are adapted to derive exact distribution functions for both classical and quantum particles at a high degeneracy limit. Quantum particles obey a non-extensive entropy $\mathcal{S} \propto \sqrt{N}$, that satisfies an Area Law: $\mathcal{S}\propto A$ in $d=2$ bulk spatial dimensions. Classical particles exhibit a definitive glass transition, similar to supercooled liquids where the configurational entropy vanishes below a finite temperature $T_K$.
format Preprint
id arxiv_https___arxiv_org_abs_2603_04823
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle The Statistical Mechanics of Indistinguishable Energy States and the Glass Transition
Akhanjee, Shimul
Statistical Mechanics
The statistical mechanics of particles that populate indistinguishable energy sub-states is explored. In particular, the mathematical treatment of the microstates differs from conventional statistical mechanics where for a given degeneracy, the energy sub-levels or sub-states are universally treated as distinguishable, and differentiated by unique quantum numbers, or addressed by distinct spatial locations. Results from combinatorial counting problems are adapted to derive exact distribution functions for both classical and quantum particles at a high degeneracy limit. Quantum particles obey a non-extensive entropy $\mathcal{S} \propto \sqrt{N}$, that satisfies an Area Law: $\mathcal{S}\propto A$ in $d=2$ bulk spatial dimensions. Classical particles exhibit a definitive glass transition, similar to supercooled liquids where the configurational entropy vanishes below a finite temperature $T_K$.
title The Statistical Mechanics of Indistinguishable Energy States and the Glass Transition
topic Statistical Mechanics
url https://arxiv.org/abs/2603.04823