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Main Authors: Gao, Jin, Chen, Rongrong, Yang, Lei, Huang, Zixiong, Liu, Dingzhao, Jia, ChengLong, Xi, Li, Xue, Desheng, Tao, Kun
Format: Preprint
Published: 2026
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Online Access:https://arxiv.org/abs/2603.07164
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author Gao, Jin
Chen, Rongrong
Yang, Lei
Huang, Zixiong
Liu, Dingzhao
Jia, ChengLong
Xi, Li
Xue, Desheng
Tao, Kun
author_facet Gao, Jin
Chen, Rongrong
Yang, Lei
Huang, Zixiong
Liu, Dingzhao
Jia, ChengLong
Xi, Li
Xue, Desheng
Tao, Kun
contents Unlike conventional approaches where topological order is statically fixed post-synthesis, we demonstrate that a single external knob-strain-can independently modulate topological order and functional responses in the Tc-adsorbed penta-hexa silicene (Tc_PH-Si) monolayer, with both properties governed by a single microscopic mechanism: momentum-space orbital-selective engineering of Tc-dxz_Si-px hybridization. Combining first-principles calculations and tight-binding models, we show that biaxial strain drives a complete topological pathway: C=1 (0) to C=0 (-2) to C = -1 (-3 to -4) to C = 0 metallic state (-6). This is exemplified by two pivotal states: a topologically critical point yet functionally optimal state at -2 strain (C=0) hosting a direct bandgap (0.17 eV) and d11 = 8.34 pm_V, and a topologically nontrivial but equally optimal state at -4 strain (C = -1) with d11 = 11.01 pm_V-three times that of MoS2. Berry curvature analysis reveals that functionality arises from local orbital hybridization strength, while topology originates from its global phase distribution. This establishes a new paradigm for materials design, transforming static functional materials into dynamically tunable quantum platforms.
format Preprint
id arxiv_https___arxiv_org_abs_2603_07164
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Orbital-Selective Engineering of Strain-Tunable Chern Insulators in Momentum Space
Gao, Jin
Chen, Rongrong
Yang, Lei
Huang, Zixiong
Liu, Dingzhao
Jia, ChengLong
Xi, Li
Xue, Desheng
Tao, Kun
Materials Science
Unlike conventional approaches where topological order is statically fixed post-synthesis, we demonstrate that a single external knob-strain-can independently modulate topological order and functional responses in the Tc-adsorbed penta-hexa silicene (Tc_PH-Si) monolayer, with both properties governed by a single microscopic mechanism: momentum-space orbital-selective engineering of Tc-dxz_Si-px hybridization. Combining first-principles calculations and tight-binding models, we show that biaxial strain drives a complete topological pathway: C=1 (0) to C=0 (-2) to C = -1 (-3 to -4) to C = 0 metallic state (-6). This is exemplified by two pivotal states: a topologically critical point yet functionally optimal state at -2 strain (C=0) hosting a direct bandgap (0.17 eV) and d11 = 8.34 pm_V, and a topologically nontrivial but equally optimal state at -4 strain (C = -1) with d11 = 11.01 pm_V-three times that of MoS2. Berry curvature analysis reveals that functionality arises from local orbital hybridization strength, while topology originates from its global phase distribution. This establishes a new paradigm for materials design, transforming static functional materials into dynamically tunable quantum platforms.
title Orbital-Selective Engineering of Strain-Tunable Chern Insulators in Momentum Space
topic Materials Science
url https://arxiv.org/abs/2603.07164