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Auteurs principaux: Ma, Xuezhi, Li, Zhipeng, Duan, Ruihuan, Deng, Zeyu, Hu, Hao, Jiang, Mengting, Zhang, Yueqian, He, Xiaoyuan, Liu, Qiushi, Liu, Qiyao, Ma, Yuan, Wei, Fengxia, Shi, Jiayu, Zheng, Chunqi, Hu, Guangwei, Lam, Ping Koy, Qiu, Chengwei, Luo, Yu, Liu, Zheng, Wang, Qian
Format: Preprint
Publié: 2026
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Accès en ligne:https://arxiv.org/abs/2603.09383
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author Ma, Xuezhi
Li, Zhipeng
Duan, Ruihuan
Deng, Zeyu
Hu, Hao
Jiang, Mengting
Zhang, Yueqian
He, Xiaoyuan
Liu, Qiushi
Liu, Qiyao
Ma, Yuan
Wei, Fengxia
Shi, Jiayu
Zheng, Chunqi
Hu, Guangwei
Lam, Ping Koy
Qiu, Chengwei
Luo, Yu
Liu, Zheng
Wang, Qian
author_facet Ma, Xuezhi
Li, Zhipeng
Duan, Ruihuan
Deng, Zeyu
Hu, Hao
Jiang, Mengting
Zhang, Yueqian
He, Xiaoyuan
Liu, Qiushi
Liu, Qiyao
Ma, Yuan
Wei, Fengxia
Shi, Jiayu
Zheng, Chunqi
Hu, Guangwei
Lam, Ping Koy
Qiu, Chengwei
Luo, Yu
Liu, Zheng
Wang, Qian
contents Predictive optical modelling of van der Waals (vdW) heterostructures is critical for meta-optics, near-field photonics and quantum technologies. At their buried interfaces, charge transfer and spatially extended screening challenge local descriptions based on layer-by-layer stacking of fixed permittivity tensors. However, such nonlocal corrections have been established mainly for plasmonic systems at ångström-nanometre scales and are often assumed negligible on optical-wavelength scales. Here we challenge this view by uncovering a mesoscopic nonlocal screening regime, extending up to ~140 nm, at buried charge-transfer interfaces in transition-metal dichalcogenide/α-molybdenum trioxide (TMDC/α-MoO3) phonon-polaritonic heterostructures. Using phonon polaritons as an ultrasensitive probe, we quantify charge transfer from polariton-wavelength shifts and find a thickness-independent saturated response as α-MoO3 is thinned. Rather than merely complicating optical modelling, this nonlocal saturation turns a design-level correction into an opportunity by yielding a transferable cross-material metric. Across more than 120 devices, this metric scales linearly with the work-function difference between the TMDC and α-MoO3. We further identify a lattice-mismatch-set energy threshold for charge transfer, revising Anderson-type band alignment for vdW interfaces.
format Preprint
id arxiv_https___arxiv_org_abs_2603_09383
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Probing mesoscopic nonlocal screening in van der Waals heterostructures with polaritons
Ma, Xuezhi
Li, Zhipeng
Duan, Ruihuan
Deng, Zeyu
Hu, Hao
Jiang, Mengting
Zhang, Yueqian
He, Xiaoyuan
Liu, Qiushi
Liu, Qiyao
Ma, Yuan
Wei, Fengxia
Shi, Jiayu
Zheng, Chunqi
Hu, Guangwei
Lam, Ping Koy
Qiu, Chengwei
Luo, Yu
Liu, Zheng
Wang, Qian
Optics
Quantum Physics
Predictive optical modelling of van der Waals (vdW) heterostructures is critical for meta-optics, near-field photonics and quantum technologies. At their buried interfaces, charge transfer and spatially extended screening challenge local descriptions based on layer-by-layer stacking of fixed permittivity tensors. However, such nonlocal corrections have been established mainly for plasmonic systems at ångström-nanometre scales and are often assumed negligible on optical-wavelength scales. Here we challenge this view by uncovering a mesoscopic nonlocal screening regime, extending up to ~140 nm, at buried charge-transfer interfaces in transition-metal dichalcogenide/α-molybdenum trioxide (TMDC/α-MoO3) phonon-polaritonic heterostructures. Using phonon polaritons as an ultrasensitive probe, we quantify charge transfer from polariton-wavelength shifts and find a thickness-independent saturated response as α-MoO3 is thinned. Rather than merely complicating optical modelling, this nonlocal saturation turns a design-level correction into an opportunity by yielding a transferable cross-material metric. Across more than 120 devices, this metric scales linearly with the work-function difference between the TMDC and α-MoO3. We further identify a lattice-mismatch-set energy threshold for charge transfer, revising Anderson-type band alignment for vdW interfaces.
title Probing mesoscopic nonlocal screening in van der Waals heterostructures with polaritons
topic Optics
Quantum Physics
url https://arxiv.org/abs/2603.09383