ALD Oxidant as A Tuning Knob for Memory Window Expansion in Ferroelectric FETs for Vertical NAND Applications

Fuente: arXiv
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Autori principali: Jeyakumar, Ranie, Venkatesan, Prasanna, Fernandes, Lance, Soliman, Salma, Ravikumar, Priyankka, Song, Taeyoung, Zhang, Chengyang, Hwang, Woohyun, Seo, Kwangyou, Lim, Suhwan, Kim, Wanki, Ha, Daewon, Yu, Shimeng, Datta, Suman, Khan, Asif
Natura: Preprint
Pubblicazione: 2026
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author Jeyakumar, Ranie
Venkatesan, Prasanna
Fernandes, Lance
Soliman, Salma
Ravikumar, Priyankka
Song, Taeyoung
Zhang, Chengyang
Hwang, Woohyun
Seo, Kwangyou
Lim, Suhwan
Kim, Wanki
Ha, Daewon
Yu, Shimeng
Datta, Suman
Khan, Asif
author_facet Jeyakumar, Ranie
Venkatesan, Prasanna
Fernandes, Lance
Soliman, Salma
Ravikumar, Priyankka
Song, Taeyoung
Zhang, Chengyang
Hwang, Woohyun
Seo, Kwangyou
Lim, Suhwan
Kim, Wanki
Ha, Daewon
Yu, Shimeng
Datta, Suman
Khan, Asif
contents Dielectric inserts are widely used to expand the memory window (MW) in ferroelectric FETs (FeFETs) for vertical NAND applications, with prior efforts focused primarily on material selection and stack positioning. Here, we demonstrate that the ALD oxidant used for the Al2O3 interlayer serves as a process-level tuning knob for MW engineering. H2O-grown Al2O3 yields a significantly larger MW (7-8 V) compared to O3 (4 V) for both gate-injection (12/3) and tunnel dielectric (8/3/8) configurations. While the tunnel dielectric (8/3/8) stack maintains robust retention up to 1e4s at 125C despite the larger MW, the gate-injection (12/3) configuration exhibits pronounced retention degradation for the H2O case. The enhanced MW is attributed to higher interlayer leakage associated with H2O-based ALD. These results establish oxidant choice as a key process parameter for co-optimizing MW and retention in ferroelectric NAND technologies.
format Preprint
id arxiv_https___arxiv_org_abs_2603_10127
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle ALD Oxidant as A Tuning Knob for Memory Window Expansion in Ferroelectric FETs for Vertical NAND Applications
Jeyakumar, Ranie
Venkatesan, Prasanna
Fernandes, Lance
Soliman, Salma
Ravikumar, Priyankka
Song, Taeyoung
Zhang, Chengyang
Hwang, Woohyun
Seo, Kwangyou
Lim, Suhwan
Kim, Wanki
Ha, Daewon
Yu, Shimeng
Datta, Suman
Khan, Asif
Materials Science
Dielectric inserts are widely used to expand the memory window (MW) in ferroelectric FETs (FeFETs) for vertical NAND applications, with prior efforts focused primarily on material selection and stack positioning. Here, we demonstrate that the ALD oxidant used for the Al2O3 interlayer serves as a process-level tuning knob for MW engineering. H2O-grown Al2O3 yields a significantly larger MW (7-8 V) compared to O3 (4 V) for both gate-injection (12/3) and tunnel dielectric (8/3/8) configurations. While the tunnel dielectric (8/3/8) stack maintains robust retention up to 1e4s at 125C despite the larger MW, the gate-injection (12/3) configuration exhibits pronounced retention degradation for the H2O case. The enhanced MW is attributed to higher interlayer leakage associated with H2O-based ALD. These results establish oxidant choice as a key process parameter for co-optimizing MW and retention in ferroelectric NAND technologies.
title ALD Oxidant as A Tuning Knob for Memory Window Expansion in Ferroelectric FETs for Vertical NAND Applications
topic Materials Science
url https://arxiv.org/abs/2603.10127