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| Hauptverfasser: | , , |
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| Format: | Preprint |
| Veröffentlicht: |
2026
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| Online-Zugang: | https://arxiv.org/abs/2603.21578 |
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| _version_ | 1866917357758185472 |
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| author | Kanabar, Naisargi Higashiya, Seiichiro Efstathiadis, Haralabos |
| author_facet | Kanabar, Naisargi Higashiya, Seiichiro Efstathiadis, Haralabos |
| contents | Garnet-type Li$_{6.25}$Al$_{0.25}$La$_3$Zr$_2$O$_{12}$ (Al-LLZO) solid electrolytes are promising for all-solid-state batteries but are limited by interfacial resistance. In this work, dense and graded tri-layer Al-LLZO electrolytes were fabricated and tested in Li/Al-LLZO/NMC(111) full cells. After 25 cycles, the tri-layer cell delivered discharge capacity of $\sim$55 mAhg$^{-1}$, nearly twice that of the dense Al-LLZO ($\sim$27 mAhg$^{-1}$). EIS showed lower initial interfacial resistance ($\sim$373 $Ω$) and improved stability. SEM confirmed a porous-dense-porous structure, while NRA revealed enhanced near-surface lithium ($\sim$75%) compared to dense Al-LLZO ($\sim$48%). These results highlight the role of microstructural grading in improving lithium distribution and cell performance. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2603_21578 |
| institution | arXiv |
| publishDate | 2026 |
| record_format | arxiv |
| spellingShingle | Improved cycling stability and lithium utilization in trilayer Al-LLZO revealed by Electrochemical cycling performance Kanabar, Naisargi Higashiya, Seiichiro Efstathiadis, Haralabos Materials Science Garnet-type Li$_{6.25}$Al$_{0.25}$La$_3$Zr$_2$O$_{12}$ (Al-LLZO) solid electrolytes are promising for all-solid-state batteries but are limited by interfacial resistance. In this work, dense and graded tri-layer Al-LLZO electrolytes were fabricated and tested in Li/Al-LLZO/NMC(111) full cells. After 25 cycles, the tri-layer cell delivered discharge capacity of $\sim$55 mAhg$^{-1}$, nearly twice that of the dense Al-LLZO ($\sim$27 mAhg$^{-1}$). EIS showed lower initial interfacial resistance ($\sim$373 $Ω$) and improved stability. SEM confirmed a porous-dense-porous structure, while NRA revealed enhanced near-surface lithium ($\sim$75%) compared to dense Al-LLZO ($\sim$48%). These results highlight the role of microstructural grading in improving lithium distribution and cell performance. |
| title | Improved cycling stability and lithium utilization in trilayer Al-LLZO revealed by Electrochemical cycling performance |
| topic | Materials Science |
| url | https://arxiv.org/abs/2603.21578 |