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Main Author: Peng, Ting
Format: Preprint
Published: 2026
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Online Access:https://arxiv.org/abs/2603.21765
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author Peng, Ting
author_facet Peng, Ting
contents This paper is accountable only to explicitly stated physical assumptions and strict logical inference. Its goal is to run a rigorous stress test of second-law claims within the Clausius framework. We work directly with \textbf{Clausius's entropy definition} for an isolated composite with energy-form conversion. Heat is withdrawn from a cold releasing subsystem with relatively small heat capacity, converted to electrical energy, and then delivered as heat to a hotter subsystem. In the ideal limit, the electrical leg contributes negligibly to Clausius entropy accounting, so the modeled reservoir Clausius sum is \[ ΔS_{\mathrm{Cl}} = Q\!\left(\frac{1}{T_B}-\frac{1}{T_A}\right) < 0. \] The paper provides a derivation, numerical illustrations, and a scope analysis; any claimed contradiction should be interpreted as a compatibility issue between different axiom sets, not as an algebraic error in the Clausius bookkeeping above.
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spellingShingle Strict Entropy Decrease of Clausius Entropy in an Isolated System with Energy-Form Conversion: Theoretical Proof, Numerical Illustration, and Critical Examination
Peng, Ting
Statistical Mechanics
This paper is accountable only to explicitly stated physical assumptions and strict logical inference. Its goal is to run a rigorous stress test of second-law claims within the Clausius framework. We work directly with \textbf{Clausius's entropy definition} for an isolated composite with energy-form conversion. Heat is withdrawn from a cold releasing subsystem with relatively small heat capacity, converted to electrical energy, and then delivered as heat to a hotter subsystem. In the ideal limit, the electrical leg contributes negligibly to Clausius entropy accounting, so the modeled reservoir Clausius sum is \[ ΔS_{\mathrm{Cl}} = Q\!\left(\frac{1}{T_B}-\frac{1}{T_A}\right) < 0. \] The paper provides a derivation, numerical illustrations, and a scope analysis; any claimed contradiction should be interpreted as a compatibility issue between different axiom sets, not as an algebraic error in the Clausius bookkeeping above.
title Strict Entropy Decrease of Clausius Entropy in an Isolated System with Energy-Form Conversion: Theoretical Proof, Numerical Illustration, and Critical Examination
topic Statistical Mechanics
url https://arxiv.org/abs/2603.21765