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Main Authors: Wu, Teng, Zhou, Qi, Zheng, Huangjie, Xie, Hehu, Xu, Zhenli
Format: Preprint
Published: 2026
Subjects:
Online Access:https://arxiv.org/abs/2603.23897
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author Wu, Teng
Zhou, Qi
Zheng, Huangjie
Xie, Hehu
Xu, Zhenli
author_facet Wu, Teng
Zhou, Qi
Zheng, Huangjie
Xie, Hehu
Xu, Zhenli
contents We present an improved version of the sum-of-Gaussians tensor neural network (SOG-TNN) architecture for solving many-electron Schrödinger equation for one-dimensional soft-Coulomb systems. Model reduction techniques are introduced to reduce the number of tensor-factorized bases under the SOG approximation of the kernel. The Slater determinant ansatz is employed so that the anti-symmetric property of the wave function can be strictly preserved. Numerical results show that the SOG-TNN achieves high accuracy with remarkably small basis sizes. Robust spectral convergence with respect to the basis size is also observed, consistently characterized by a mixed algebraic-exponential model for the error decay. These findings validate that the SOG-TNN architecture provides an ultra-efficient and low-rank representation of complex multi-electron wave functions, shedding light on high-fidelity quantum calculations in larger-scale many-electron systems.
format Preprint
id arxiv_https___arxiv_org_abs_2603_23897
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Spectral convergence of sum-of-Gaussians tensor neural networks for many-electron Schrödinger equation
Wu, Teng
Zhou, Qi
Zheng, Huangjie
Xie, Hehu
Xu, Zhenli
Chemical Physics
We present an improved version of the sum-of-Gaussians tensor neural network (SOG-TNN) architecture for solving many-electron Schrödinger equation for one-dimensional soft-Coulomb systems. Model reduction techniques are introduced to reduce the number of tensor-factorized bases under the SOG approximation of the kernel. The Slater determinant ansatz is employed so that the anti-symmetric property of the wave function can be strictly preserved. Numerical results show that the SOG-TNN achieves high accuracy with remarkably small basis sizes. Robust spectral convergence with respect to the basis size is also observed, consistently characterized by a mixed algebraic-exponential model for the error decay. These findings validate that the SOG-TNN architecture provides an ultra-efficient and low-rank representation of complex multi-electron wave functions, shedding light on high-fidelity quantum calculations in larger-scale many-electron systems.
title Spectral convergence of sum-of-Gaussians tensor neural networks for many-electron Schrödinger equation
topic Chemical Physics
url https://arxiv.org/abs/2603.23897