Distinguishing impurity-induced bound states from Majorana-like zero-energy peaks in strained CsCa2Fe4As4F2 by scanning tunneling microscopy

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Main Authors: Li, Mingzhe, Gong, Jiashuo, Li, Huaxun, Zhang, Jiakang, Li, Yuanji, Yin, Ruotong, Wang, Shiyuan, Cao, Guanghan, Feng, Dong-Lai, Yan, Ya-Jun
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Published: 2026
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author Li, Mingzhe
Gong, Jiashuo
Li, Huaxun
Zhang, Jiakang
Li, Yuanji
Yin, Ruotong
Wang, Shiyuan
Cao, Guanghan
Feng, Dong-Lai
Yan, Ya-Jun
author_facet Li, Mingzhe
Gong, Jiashuo
Li, Huaxun
Zhang, Jiakang
Li, Yuanji
Yin, Ruotong
Wang, Shiyuan
Cao, Guanghan
Feng, Dong-Lai
Yan, Ya-Jun
contents Iron-based superconductors offer a versatile platform for exploring topological superconductivity and Majorana zero modes (MZMs), with experimental confirmations in Fe(Te,Se), (Li,Fe)OHFeSe and CaKFe4As4 at ambient pressure, as well as in LiFeAs under local strain. The related properties in other iron-based superconductors still need to be explored, especially under the application of local strain. In this study, we conduct scanning tunneling microscopy/spectroscopy measurements on CsCa2Fe4As4F2 crystals under unidirectional local strain. A fully developed superconducting gap with multiple pairs of coherence peaks are observed, and the gap sizes can be significantly modulated by local strain. Spectroscopic measurements on various types of defects including the nonmagnetic Cs-site vacancies consistently reveal pair-breaking effects. These phenomena support a fully gapped multiband superconductivity scenario with sign-changing. Notably, a sharp zero-energy conductance peak (ZECP) is universally observed on a particular type of defects by using a metallic tip, resembling the MZMs observed at interstitial Fe atoms in Fe(Te,Se) [Nat. Phys. 11, 543 (2015)]. However, by using a superconducting tip to enhance energy resolution as well as by studying the ZECP evolution as functions of magnetic field and tunneling transmissivity, we demonstrate that the ZECP originates from nearly degenerate Yu-Shiba-Rusinov states rather than MZMs. Our study not only provides more insights into the superconducting pairing symmetry of CsCa2Fe4As4F2, but also establishes systematic experimental methods for identifying weak impurity state signals and discerning the physical origins of ZECPs.
format Preprint
id arxiv_https___arxiv_org_abs_2603_27217
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Distinguishing impurity-induced bound states from Majorana-like zero-energy peaks in strained CsCa2Fe4As4F2 by scanning tunneling microscopy
Li, Mingzhe
Gong, Jiashuo
Li, Huaxun
Zhang, Jiakang
Li, Yuanji
Yin, Ruotong
Wang, Shiyuan
Cao, Guanghan
Feng, Dong-Lai
Yan, Ya-Jun
Superconductivity
Iron-based superconductors offer a versatile platform for exploring topological superconductivity and Majorana zero modes (MZMs), with experimental confirmations in Fe(Te,Se), (Li,Fe)OHFeSe and CaKFe4As4 at ambient pressure, as well as in LiFeAs under local strain. The related properties in other iron-based superconductors still need to be explored, especially under the application of local strain. In this study, we conduct scanning tunneling microscopy/spectroscopy measurements on CsCa2Fe4As4F2 crystals under unidirectional local strain. A fully developed superconducting gap with multiple pairs of coherence peaks are observed, and the gap sizes can be significantly modulated by local strain. Spectroscopic measurements on various types of defects including the nonmagnetic Cs-site vacancies consistently reveal pair-breaking effects. These phenomena support a fully gapped multiband superconductivity scenario with sign-changing. Notably, a sharp zero-energy conductance peak (ZECP) is universally observed on a particular type of defects by using a metallic tip, resembling the MZMs observed at interstitial Fe atoms in Fe(Te,Se) [Nat. Phys. 11, 543 (2015)]. However, by using a superconducting tip to enhance energy resolution as well as by studying the ZECP evolution as functions of magnetic field and tunneling transmissivity, we demonstrate that the ZECP originates from nearly degenerate Yu-Shiba-Rusinov states rather than MZMs. Our study not only provides more insights into the superconducting pairing symmetry of CsCa2Fe4As4F2, but also establishes systematic experimental methods for identifying weak impurity state signals and discerning the physical origins of ZECPs.
title Distinguishing impurity-induced bound states from Majorana-like zero-energy peaks in strained CsCa2Fe4As4F2 by scanning tunneling microscopy
topic Superconductivity
url https://arxiv.org/abs/2603.27217