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Main Authors: Liu, Yi, Xu, Chen-Chao, Bao, Jin-Ke, Lv, Bai-Jiang, Li, Hao, Li, Jing, Lin, Yi-Qiang, Li, Hua-Xun, Lu, Yi-Ming, Zhao, Xin-Yu, Yang, Wu-Zhang, Zhang, Zhen-Yi, Chen, Xian-Yan, Jiao, Wen-he, Liu, Ji-Yong, Zhu, Bai-Ren, Cao, Guang-Han
Format: Preprint
Published: 2026
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Online Access:https://arxiv.org/abs/2604.02114
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author Liu, Yi
Xu, Chen-Chao
Bao, Jin-Ke
Lv, Bai-Jiang
Li, Hao
Li, Jing
Lin, Yi-Qiang
Li, Hua-Xun
Lu, Yi-Ming
Zhao, Xin-Yu
Yang, Wu-Zhang
Zhang, Zhen-Yi
Chen, Xian-Yan
Jiao, Wen-he
Liu, Ji-Yong
Zhu, Bai-Ren
Cao, Guang-Han
author_facet Liu, Yi
Xu, Chen-Chao
Bao, Jin-Ke
Lv, Bai-Jiang
Li, Hao
Li, Jing
Lin, Yi-Qiang
Li, Hua-Xun
Lu, Yi-Ming
Zhao, Xin-Yu
Yang, Wu-Zhang
Zhang, Zhen-Yi
Chen, Xian-Yan
Jiao, Wen-he
Liu, Ji-Yong
Zhu, Bai-Ren
Cao, Guang-Han
contents Metal-to-insulator transitions (MITs), particularly near room temperature, have been extensively studied in nonmagnetic and conventional ferromagnetic and antiferromagnetic systems, yet the co-emergence of MIT and altermagnetism (AM) remains unexplored. Here, a layered chromium-based compound CsCr$_2$S$_2$O that realizes this coexistence was synthesized. It crystalizes in CeCr$_2$Si$_2$C-type structure with Cr moments orders in a C-type antiferromagnetic configuration below $T_\mathrm{N}$ = 326 K, constituting a room-temperature d-wave altermagnet. In the altermagnetic state, a subsequent Verwey-type MIT appears at $T_\mathrm{MI}$ = 305 K, driven by a tetragonal-to-orthorhombic structural distortion and stripe charge ordering of Cr$^{+2}$/Cr$^{+3}$ ions, while maintaining its altermagnetic character. First-principles calculations show moment-dependent spin-split electronic structures with maximum splitting energies of ~0.6 eV and ~0.3 eV in the metallic and insulating states, respectively. Our work links the two prominent phenomena, MIT and AM, in a single material, establishing a new platform for potential spintronic applications.
format Preprint
id arxiv_https___arxiv_org_abs_2604_02114
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Altermagnetism and Room-Temperature Metal-to-Insulator Transition in CsCr$_2$S$_2$O
Liu, Yi
Xu, Chen-Chao
Bao, Jin-Ke
Lv, Bai-Jiang
Li, Hao
Li, Jing
Lin, Yi-Qiang
Li, Hua-Xun
Lu, Yi-Ming
Zhao, Xin-Yu
Yang, Wu-Zhang
Zhang, Zhen-Yi
Chen, Xian-Yan
Jiao, Wen-he
Liu, Ji-Yong
Zhu, Bai-Ren
Cao, Guang-Han
Materials Science
Strongly Correlated Electrons
Metal-to-insulator transitions (MITs), particularly near room temperature, have been extensively studied in nonmagnetic and conventional ferromagnetic and antiferromagnetic systems, yet the co-emergence of MIT and altermagnetism (AM) remains unexplored. Here, a layered chromium-based compound CsCr$_2$S$_2$O that realizes this coexistence was synthesized. It crystalizes in CeCr$_2$Si$_2$C-type structure with Cr moments orders in a C-type antiferromagnetic configuration below $T_\mathrm{N}$ = 326 K, constituting a room-temperature d-wave altermagnet. In the altermagnetic state, a subsequent Verwey-type MIT appears at $T_\mathrm{MI}$ = 305 K, driven by a tetragonal-to-orthorhombic structural distortion and stripe charge ordering of Cr$^{+2}$/Cr$^{+3}$ ions, while maintaining its altermagnetic character. First-principles calculations show moment-dependent spin-split electronic structures with maximum splitting energies of ~0.6 eV and ~0.3 eV in the metallic and insulating states, respectively. Our work links the two prominent phenomena, MIT and AM, in a single material, establishing a new platform for potential spintronic applications.
title Altermagnetism and Room-Temperature Metal-to-Insulator Transition in CsCr$_2$S$_2$O
topic Materials Science
Strongly Correlated Electrons
url https://arxiv.org/abs/2604.02114