Monitoring Volatile Evolution in Disrupting Comet D/2021 A1 (Leonard) with NOEMA and APEX

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Auteurs principaux: Proudkii, Timothy N., Roth, Nathan X., Boissier, Jérémie, Bockelée-Morvan, Dominique, Biver, Nicolas, Charnley, Steven B., Milam, Stefanie N., Cordiner, Martin A., DiSanti, Michael A., Bonev, Boncho P., Russo, Neil Dello
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Publié: 2026
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author Proudkii, Timothy N.
Roth, Nathan X.
Boissier, Jérémie
Bockelée-Morvan, Dominique
Biver, Nicolas
Charnley, Steven B.
Milam, Stefanie N.
Cordiner, Martin A.
DiSanti, Michael A.
Bonev, Boncho P.
Russo, Neil Dello
author_facet Proudkii, Timothy N.
Roth, Nathan X.
Boissier, Jérémie
Bockelée-Morvan, Dominique
Biver, Nicolas
Charnley, Steven B.
Milam, Stefanie N.
Cordiner, Martin A.
DiSanti, Michael A.
Bonev, Boncho P.
Russo, Neil Dello
contents We report a pre-perihelion survey of volatile emissions from comet D/2021 A1 (Leonard) with the Northern Extended Millimeter Array (NOEMA; UT 2021 Nov. 5, 21, and Dec. 1) and the Atacama Pathfinder Experiment (APEX; UT 2021 Dec. 9-10), spanning heliocentric distances ($r_H$) from 1.3 to 0.80 au. We securely detected HCN and CS and place 3$σ$ upper limits on CH$_3$OH, H$_2$CO, and CO abundances. Line kinematics and NOEMA spatial constraints indicate that HCN was released at or near the nucleus (parent scale length $<300$ km), while CS showed higher gas expansion velocities and mixing ratios that increased with decreasing $r_H$ $-$ consistent with production from a distributed source. Across our campaign, CS mixing ratios relative to H$_2$O increased by a factor of $\sim$5, from $0.02 \pm 0.01\%$ at $r_H$ = 1.3 au to $0.10\pm0.02\%$ by $r_H$ = 0.80 au. HCN mixing ratios in our data rose modestly, from $0.04 \pm 0.02\%$ at $r_H$ = 1.3 au to $0.07 \pm 0.02\%$ by $r_H$ = 0.81 au. However, contemporaneous measurements from other facilities placed HCN consistently at a higher absolute level ($\sim\!0.08\%$) with additional variability. Once cross-facility measurements were included, the HCN abundance showed no statistically robust monotonic dependence on $r_H$. Variability in both species during the mid-December outbursts and fragmentation suggests that D/2021 A1's volatile evolution reflected not only solar insolation but also disruption processes, underscoring the value of multi-epoch, multi-instrument monitoring to capture rapid, species-dependent changes.
format Preprint
id arxiv_https___arxiv_org_abs_2604_02613
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Monitoring Volatile Evolution in Disrupting Comet D/2021 A1 (Leonard) with NOEMA and APEX
Proudkii, Timothy N.
Roth, Nathan X.
Boissier, Jérémie
Bockelée-Morvan, Dominique
Biver, Nicolas
Charnley, Steven B.
Milam, Stefanie N.
Cordiner, Martin A.
DiSanti, Michael A.
Bonev, Boncho P.
Russo, Neil Dello
Earth and Planetary Astrophysics
We report a pre-perihelion survey of volatile emissions from comet D/2021 A1 (Leonard) with the Northern Extended Millimeter Array (NOEMA; UT 2021 Nov. 5, 21, and Dec. 1) and the Atacama Pathfinder Experiment (APEX; UT 2021 Dec. 9-10), spanning heliocentric distances ($r_H$) from 1.3 to 0.80 au. We securely detected HCN and CS and place 3$σ$ upper limits on CH$_3$OH, H$_2$CO, and CO abundances. Line kinematics and NOEMA spatial constraints indicate that HCN was released at or near the nucleus (parent scale length $<300$ km), while CS showed higher gas expansion velocities and mixing ratios that increased with decreasing $r_H$ $-$ consistent with production from a distributed source. Across our campaign, CS mixing ratios relative to H$_2$O increased by a factor of $\sim$5, from $0.02 \pm 0.01\%$ at $r_H$ = 1.3 au to $0.10\pm0.02\%$ by $r_H$ = 0.80 au. HCN mixing ratios in our data rose modestly, from $0.04 \pm 0.02\%$ at $r_H$ = 1.3 au to $0.07 \pm 0.02\%$ by $r_H$ = 0.81 au. However, contemporaneous measurements from other facilities placed HCN consistently at a higher absolute level ($\sim\!0.08\%$) with additional variability. Once cross-facility measurements were included, the HCN abundance showed no statistically robust monotonic dependence on $r_H$. Variability in both species during the mid-December outbursts and fragmentation suggests that D/2021 A1's volatile evolution reflected not only solar insolation but also disruption processes, underscoring the value of multi-epoch, multi-instrument monitoring to capture rapid, species-dependent changes.
title Monitoring Volatile Evolution in Disrupting Comet D/2021 A1 (Leonard) with NOEMA and APEX
topic Earth and Planetary Astrophysics
url https://arxiv.org/abs/2604.02613