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Autori principali: Jhamnani, Mayur, Redrouthu, Venkata SubbaRao, Carvalho, Jose P., Feldman, Ethan, Nielsen, Anders B., Kumar, Phani, Nielsen, Niels Chr., Madhu, P. K., Equbal, Asif
Natura: Preprint
Pubblicazione: 2026
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Accesso online:https://arxiv.org/abs/2604.04789
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author Jhamnani, Mayur
Redrouthu, Venkata SubbaRao
Carvalho, Jose P.
Feldman, Ethan
Nielsen, Anders B.
Kumar, Phani
Nielsen, Niels Chr.
Madhu, P. K.
Equbal, Asif
author_facet Jhamnani, Mayur
Redrouthu, Venkata SubbaRao
Carvalho, Jose P.
Feldman, Ethan
Nielsen, Anders B.
Kumar, Phani
Nielsen, Niels Chr.
Madhu, P. K.
Equbal, Asif
contents PulsePol is an elegantly designed pulse-sequence-based quantum control scheme that enables polarization transfer between electron and nuclear spins, for example, in nitrogen-vacancy (NV) centers. However, previous analyses of PulsePol assumed very strong, near-ideal, instantaneous microwave pulses, which is rarely achievable at higher magnetic fields. We revisit the PulsePol scheme under finite-pulse constraints and show that its performance significantly degrades due to finite-pulse effects. Using bimodal Floquet theory, we identify the symmetry-breaking mechanism responsible for this deterioration in fidelity. By phase adjustment, we reestablish the proper symmetry of the interaction-frame spin Hamiltonian, leading to a sequence called Q-PulsePol, where "Q" reflects the restored quadrature symmetry. Our results demonstrate robustness to finite-pulse effects and improved polarization transfer efficiency, establishing Q-PulsePol as a practical and reliable scheme for bulk hyperpolarization of nuclear spins in solids using a single-mode (zero-quantum or double-quantum) transfer. This work bridges idealized quantum control with realistic pulse engineering, establishing design rules for spin-based quantum control protocols.
format Preprint
id arxiv_https___arxiv_org_abs_2604_04789
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Quadrature-Symmetric PulsePol for Robust Quantum Control Beyond the Ideal Pulse Approximation
Jhamnani, Mayur
Redrouthu, Venkata SubbaRao
Carvalho, Jose P.
Feldman, Ethan
Nielsen, Anders B.
Kumar, Phani
Nielsen, Niels Chr.
Madhu, P. K.
Equbal, Asif
Quantum Physics
Other Condensed Matter
PulsePol is an elegantly designed pulse-sequence-based quantum control scheme that enables polarization transfer between electron and nuclear spins, for example, in nitrogen-vacancy (NV) centers. However, previous analyses of PulsePol assumed very strong, near-ideal, instantaneous microwave pulses, which is rarely achievable at higher magnetic fields. We revisit the PulsePol scheme under finite-pulse constraints and show that its performance significantly degrades due to finite-pulse effects. Using bimodal Floquet theory, we identify the symmetry-breaking mechanism responsible for this deterioration in fidelity. By phase adjustment, we reestablish the proper symmetry of the interaction-frame spin Hamiltonian, leading to a sequence called Q-PulsePol, where "Q" reflects the restored quadrature symmetry. Our results demonstrate robustness to finite-pulse effects and improved polarization transfer efficiency, establishing Q-PulsePol as a practical and reliable scheme for bulk hyperpolarization of nuclear spins in solids using a single-mode (zero-quantum or double-quantum) transfer. This work bridges idealized quantum control with realistic pulse engineering, establishing design rules for spin-based quantum control protocols.
title Quadrature-Symmetric PulsePol for Robust Quantum Control Beyond the Ideal Pulse Approximation
topic Quantum Physics
Other Condensed Matter
url https://arxiv.org/abs/2604.04789