Spectral Softening and the Structural Breakdown of Thermodynamic Equilibrium
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arXiv
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| Natura: | Preprint |
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2026
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| _version_ | 1866915932361719808 |
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| author | Kim, Ilki |
| author_facet | Kim, Ilki |
| contents | Under sufficiently slow driving, thermodynamics predicts reversible evolution through a sequence of equilibrium states. We show that this expectation fails near spectral degeneracy in driven quadratic Hamiltonian systems. As the soft-mode frequency collapses, the intrinsic dynamical timescale diverges and quadratic confinement is lost, leading to a breakdown of timescale separation and the failure of adiabatic following even under arbitrarily slow driving. More precisely, adiabaticity is lost once the soft-mode frequency falls below a finite, drive-dependent threshold, implying that the breakdown extends over a finite regime rather than being confined to a singular limit. Crucially, this dynamical instability is accompanied by a divergence of the canonical partition function, rendering equilibrium ensembles ill-defined and eliminating the foundation of quasistatic thermodynamic processes. This breakdown does not arise from unbounded Hamiltonians or critical slowing down, but emerges structurally from spectral softening within a bounded quadratic system. Analysis of the Wigner phase-space representation, together with its classical counterpart, reveals the same singular structure, demonstrating that this limitation is not uniquely quantum but originates from the underlying Hamiltonian phase-space geometry. These results show that thermodynamic reversibility is fundamentally constrained, as a direct consequence of the breakdown of equilibrium, whenever spectral softening removes an intrinsic frequency scale. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2604_10216 |
| institution | arXiv |
| publishDate | 2026 |
| record_format | arxiv |
| spellingShingle | Spectral Softening and the Structural Breakdown of Thermodynamic Equilibrium Kim, Ilki Statistical Mechanics Under sufficiently slow driving, thermodynamics predicts reversible evolution through a sequence of equilibrium states. We show that this expectation fails near spectral degeneracy in driven quadratic Hamiltonian systems. As the soft-mode frequency collapses, the intrinsic dynamical timescale diverges and quadratic confinement is lost, leading to a breakdown of timescale separation and the failure of adiabatic following even under arbitrarily slow driving. More precisely, adiabaticity is lost once the soft-mode frequency falls below a finite, drive-dependent threshold, implying that the breakdown extends over a finite regime rather than being confined to a singular limit. Crucially, this dynamical instability is accompanied by a divergence of the canonical partition function, rendering equilibrium ensembles ill-defined and eliminating the foundation of quasistatic thermodynamic processes. This breakdown does not arise from unbounded Hamiltonians or critical slowing down, but emerges structurally from spectral softening within a bounded quadratic system. Analysis of the Wigner phase-space representation, together with its classical counterpart, reveals the same singular structure, demonstrating that this limitation is not uniquely quantum but originates from the underlying Hamiltonian phase-space geometry. These results show that thermodynamic reversibility is fundamentally constrained, as a direct consequence of the breakdown of equilibrium, whenever spectral softening removes an intrinsic frequency scale. |
| title | Spectral Softening and the Structural Breakdown of Thermodynamic Equilibrium |
| topic | Statistical Mechanics |
| url | https://arxiv.org/abs/2604.10216 |