ALD W-Doped SnO$_2$ TFTs for Indium-Free BEOL Electronics

Fuente: arXiv
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Autores principales: Patil, Mansi Anil, Dhoble, Devarshi, Kubakaddi, Shivaram, Raturi, Mamta, Villena, Marco A, Thareja, Gaurav, Lodha, Saurabh
Formato: Preprint
Publicado: 2026
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author Patil, Mansi Anil
Dhoble, Devarshi
Kubakaddi, Shivaram
Raturi, Mamta
Villena, Marco A
Thareja, Gaurav
Lodha, Saurabh
author_facet Patil, Mansi Anil
Dhoble, Devarshi
Kubakaddi, Shivaram
Raturi, Mamta
Villena, Marco A
Thareja, Gaurav
Lodha, Saurabh
contents This work reports back-end-of-line (BEOL) compatible, thin-film transistors (TFTs) with sub-10 nm tungsten-doped tin oxide (TWO) channels deposited by atomic layer deposition (ALD) at 150 $^\circ$C. TFTs with undoped SnO$_{\mathrm{x}}$, undoped WO$_{\mathrm{x}}$, and W-doped SnO$_{\mathrm{x}}$ channels with W concentrations of 5% and 10% were investigated. TFT with 10% W doping exhibited the best electrostatic control and overall device performance. Post-fabrication O$_{\mathrm{2}}$ annealing at 300 $^\circ$C for 5 minutes significantly enhanced device characteristics, reducing the subthreshold swing (SS) by nearly 2$\times$, increasing the I$_{\mathrm{on}}$/I$_{\mathrm{off}}$ ratio from $10^7$ to $10^9$, decreasing hysteresis by nearly 3$\times$ and positive bias stress-induced threshold shift by over 2$\times$ to a low value of 93 mV at a stress field of 4 MV/cm. Kinetic Monte Carlo simulations using Ginestra$^{\mathrm{TM}}$ support the experimental observations and attribute the bias instability to charge trapping in the gate dielectric and at the interface. This work demonstrates low-temperature ALD-grown TWO TFTs as a promising indium-free platform for BEOL and monolithic 3D integration.
format Preprint
id arxiv_https___arxiv_org_abs_2604_11333
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle ALD W-Doped SnO$_2$ TFTs for Indium-Free BEOL Electronics
Patil, Mansi Anil
Dhoble, Devarshi
Kubakaddi, Shivaram
Raturi, Mamta
Villena, Marco A
Thareja, Gaurav
Lodha, Saurabh
Applied Physics
Materials Science
This work reports back-end-of-line (BEOL) compatible, thin-film transistors (TFTs) with sub-10 nm tungsten-doped tin oxide (TWO) channels deposited by atomic layer deposition (ALD) at 150 $^\circ$C. TFTs with undoped SnO$_{\mathrm{x}}$, undoped WO$_{\mathrm{x}}$, and W-doped SnO$_{\mathrm{x}}$ channels with W concentrations of 5% and 10% were investigated. TFT with 10% W doping exhibited the best electrostatic control and overall device performance. Post-fabrication O$_{\mathrm{2}}$ annealing at 300 $^\circ$C for 5 minutes significantly enhanced device characteristics, reducing the subthreshold swing (SS) by nearly 2$\times$, increasing the I$_{\mathrm{on}}$/I$_{\mathrm{off}}$ ratio from $10^7$ to $10^9$, decreasing hysteresis by nearly 3$\times$ and positive bias stress-induced threshold shift by over 2$\times$ to a low value of 93 mV at a stress field of 4 MV/cm. Kinetic Monte Carlo simulations using Ginestra$^{\mathrm{TM}}$ support the experimental observations and attribute the bias instability to charge trapping in the gate dielectric and at the interface. This work demonstrates low-temperature ALD-grown TWO TFTs as a promising indium-free platform for BEOL and monolithic 3D integration.
title ALD W-Doped SnO$_2$ TFTs for Indium-Free BEOL Electronics
topic Applied Physics
Materials Science
url https://arxiv.org/abs/2604.11333