Thermodynamic Geometry of Relaxation

Fuente: arXiv
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Hauptverfasser: Wang, Hao, Zhao, Li, Deng, Shuai, Ma, Yu-Han
Format: Preprint
Veröffentlicht: 2026
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author Wang, Hao
Zhao, Li
Deng, Shuai
Ma, Yu-Han
author_facet Wang, Hao
Zhao, Li
Deng, Shuai
Ma, Yu-Han
contents While the geometry of equilibrium states and driven non-equilibrium processes is clearly understood, a geometric description for relaxation towards equilibrium is still lacking. Here, we propose a thermo-geometric measure based on the Rayleigh quotient, reformulating relaxation as a fundamental competition between entropic stiffness and frictional dissipation. Taking a van der Waals gas with two dissipation channels as an example, we explicitly demonstrate its relaxation landscape. Particularly, we find that upon approaching the critical temperature $T_c$, the slow-mode relaxation rate vanishes linearly as $λ_s \propto (T-T_c)/T_c$, indicating critical slowing down. This study completes the thermodynamic geometry framework, providing a general tool for characterizing the relaxation dynamics of complex systems.
format Preprint
id arxiv_https___arxiv_org_abs_2604_15000
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Thermodynamic Geometry of Relaxation
Wang, Hao
Zhao, Li
Deng, Shuai
Ma, Yu-Han
Statistical Mechanics
Classical Physics
Quantum Physics
While the geometry of equilibrium states and driven non-equilibrium processes is clearly understood, a geometric description for relaxation towards equilibrium is still lacking. Here, we propose a thermo-geometric measure based on the Rayleigh quotient, reformulating relaxation as a fundamental competition between entropic stiffness and frictional dissipation. Taking a van der Waals gas with two dissipation channels as an example, we explicitly demonstrate its relaxation landscape. Particularly, we find that upon approaching the critical temperature $T_c$, the slow-mode relaxation rate vanishes linearly as $λ_s \propto (T-T_c)/T_c$, indicating critical slowing down. This study completes the thermodynamic geometry framework, providing a general tool for characterizing the relaxation dynamics of complex systems.
title Thermodynamic Geometry of Relaxation
topic Statistical Mechanics
Classical Physics
Quantum Physics
url https://arxiv.org/abs/2604.15000