How the Hahn-Banach Theorem Sheds Bright Light on Fundamental Questions in Classical Thermodynamics

Fuente: arXiv
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Autori principali: Feinberg, Martin, Lavine, Richard B.
Natura: Preprint
Pubblicazione: 2026
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author Feinberg, Martin
Lavine, Richard B.
author_facet Feinberg, Martin
Lavine, Richard B.
contents The Hahn-Banach Theorem, a cornerstone of modern functional analysis, is a natural companion of the Second Law of Thermodynamics. From a Kelvin-Planck version of the Second Law, the Hahn-Banach Theorem delivers, immediately and simultaneously, entropy and thermodynamic-temperature functions of the local material state such that the Clausius-Duhem inequality is satisfied for every process a particular material might admit. For \emph{existence} of such functions there is no need at all to require that their domain be restricted to states of equilibrium. However, the Hahn-Banach Theorem also indicates that for \emph{uniqueness} of such a pair of functions across the entire state-space domain, every state must be visited by a reversible process. This review is intended to help make accessible to both thermodynamics scholars and mathematicians the remarkable interplay of the Hahn-Banach Theorem and the Second Law.
format Preprint
id arxiv_https___arxiv_org_abs_2604_22717
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle How the Hahn-Banach Theorem Sheds Bright Light on Fundamental Questions in Classical Thermodynamics
Feinberg, Martin
Lavine, Richard B.
Classical Physics
Mathematical Physics
Dynamical Systems
Functional Analysis
Chemical Physics
The Hahn-Banach Theorem, a cornerstone of modern functional analysis, is a natural companion of the Second Law of Thermodynamics. From a Kelvin-Planck version of the Second Law, the Hahn-Banach Theorem delivers, immediately and simultaneously, entropy and thermodynamic-temperature functions of the local material state such that the Clausius-Duhem inequality is satisfied for every process a particular material might admit. For \emph{existence} of such functions there is no need at all to require that their domain be restricted to states of equilibrium. However, the Hahn-Banach Theorem also indicates that for \emph{uniqueness} of such a pair of functions across the entire state-space domain, every state must be visited by a reversible process. This review is intended to help make accessible to both thermodynamics scholars and mathematicians the remarkable interplay of the Hahn-Banach Theorem and the Second Law.
title How the Hahn-Banach Theorem Sheds Bright Light on Fundamental Questions in Classical Thermodynamics
topic Classical Physics
Mathematical Physics
Dynamical Systems
Functional Analysis
Chemical Physics
url https://arxiv.org/abs/2604.22717