Nanoscale Sensing of Solid-State Samples with High Frequency Resolution

Fuente: arXiv
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Bibliographic Details
Main Authors: Alsina-Bolívar, P., Iriarte-Zendoia, I., Bucher, D. B., Casanova, J.
Format: Preprint
Published: 2026
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author Alsina-Bolívar, P.
Iriarte-Zendoia, I.
Bucher, D. B.
Casanova, J.
author_facet Alsina-Bolívar, P.
Iriarte-Zendoia, I.
Bucher, D. B.
Casanova, J.
contents To meet the growing demand for nanoscale surface analysis, nitrogen-vacancy (NV) centers offer a high-sensitivity alternative by leveraging their ability to operate in immediate proximity to the sample. In this work, we propose a quantum control protocol designed to overcome the inherent challenges of solid-state environments, specifically by mitigating anisotropy and strong dipole-dipole interactions to enable the detection of isotropic chemical shifts at the nanoscale. To achieve this, our scheme synchronizes a slowly rotating magnetic field with tailored RF decoupling and MW control of the NV sensors. We provide an analytical mapping that explicitly links the measured spectrum to the control sequence features and the underlying system parameters, enabling a straightforward characterization of the sample.
format Preprint
id arxiv_https___arxiv_org_abs_2604_25660
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Nanoscale Sensing of Solid-State Samples with High Frequency Resolution
Alsina-Bolívar, P.
Iriarte-Zendoia, I.
Bucher, D. B.
Casanova, J.
Quantum Physics
To meet the growing demand for nanoscale surface analysis, nitrogen-vacancy (NV) centers offer a high-sensitivity alternative by leveraging their ability to operate in immediate proximity to the sample. In this work, we propose a quantum control protocol designed to overcome the inherent challenges of solid-state environments, specifically by mitigating anisotropy and strong dipole-dipole interactions to enable the detection of isotropic chemical shifts at the nanoscale. To achieve this, our scheme synchronizes a slowly rotating magnetic field with tailored RF decoupling and MW control of the NV sensors. We provide an analytical mapping that explicitly links the measured spectrum to the control sequence features and the underlying system parameters, enabling a straightforward characterization of the sample.
title Nanoscale Sensing of Solid-State Samples with High Frequency Resolution
topic Quantum Physics
url https://arxiv.org/abs/2604.25660