Formation of gaseous, doubly charged cerium monofluoride CeF$^{2+}$ and its sensitivity to new physics

Fuente: arXiv
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Hauptverfasser: Simpson, R., Zülch, C., Ng, K. B., Belosevic, I., Charles, C., Justus, P., Berger, R., Malbrunot-Ettenauer, S., Kwiatkowski, A. A., Reiter, M. P., Ash, J., Babcock, C., Bergmann, J., Brisley, E., Cardona, J. D., Chambers, C., Czihaly, A., Gottberg, A., Kakkar, S., Lassen, J., Milán, F. Maldonado, Mollaebrahimi, A., Radchenko, V., Taylor, E., Teigelhöfer, A., Walls, C., Weaver, A., Weligampola, P.
Format: Preprint
Veröffentlicht: 2026
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author Simpson, R.
Zülch, C.
Ng, K. B.
Belosevic, I.
Charles, C.
Justus, P.
Berger, R.
Malbrunot-Ettenauer, S.
Kwiatkowski, A. A.
Reiter, M. P.
Ash, J.
Babcock, C.
Bergmann, J.
Brisley, E.
Cardona, J. D.
Chambers, C.
Czihaly, A.
Gottberg, A.
Kakkar, S.
Lassen, J.
Milán, F. Maldonado
Mollaebrahimi, A.
Radchenko, V.
Taylor, E.
Teigelhöfer, A.
Walls, C.
Weaver, A.
Weligampola, P.
author_facet Simpson, R.
Zülch, C.
Ng, K. B.
Belosevic, I.
Charles, C.
Justus, P.
Berger, R.
Malbrunot-Ettenauer, S.
Kwiatkowski, A. A.
Reiter, M. P.
Ash, J.
Babcock, C.
Bergmann, J.
Brisley, E.
Cardona, J. D.
Chambers, C.
Czihaly, A.
Gottberg, A.
Kakkar, S.
Lassen, J.
Milán, F. Maldonado
Mollaebrahimi, A.
Radchenko, V.
Taylor, E.
Teigelhöfer, A.
Walls, C.
Weaver, A.
Weligampola, P.
contents Tricationic protactinium monofluoride ($^{229}$PaF$^{3+}$) has been proposed as a candidate for probing physics beyond the Standard Model of particle physics. Since studies with $^{229}$PaF$^{3+}$ require significant experimental advances, we exploit the stable, valence-isoelectronic dicationic cerium monofluoride (CeF$^{2+}$) as a surrogate. Gas-phase fluorinated-cerium molecular ions are formed and identified using the Off-Line Ion Source and TITAN mass measurement facilities at TRIUMF. Quantum chemical calculations are performed on the electronic structure of CeF$^{2+}$, revealing a parallel to that of $^{229}$PaF$^{3+}$. Moreover, these calculations provide estimates on the sensitivity of CeF$^{2+}$ itself to various $\mathcal{P,T}$-odd properties. A brief discourse on the specifics of the quantum control of CeF$^{2+}$ is presented which anticipates future searches for symmetry violations.
format Preprint
id arxiv_https___arxiv_org_abs_2604_26109
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Formation of gaseous, doubly charged cerium monofluoride CeF$^{2+}$ and its sensitivity to new physics
Simpson, R.
Zülch, C.
Ng, K. B.
Belosevic, I.
Charles, C.
Justus, P.
Berger, R.
Malbrunot-Ettenauer, S.
Kwiatkowski, A. A.
Reiter, M. P.
Ash, J.
Babcock, C.
Bergmann, J.
Brisley, E.
Cardona, J. D.
Chambers, C.
Czihaly, A.
Gottberg, A.
Kakkar, S.
Lassen, J.
Milán, F. Maldonado
Mollaebrahimi, A.
Radchenko, V.
Taylor, E.
Teigelhöfer, A.
Walls, C.
Weaver, A.
Weligampola, P.
Atomic Physics
Nuclear Experiment
Nuclear Theory
Quantum Physics
Tricationic protactinium monofluoride ($^{229}$PaF$^{3+}$) has been proposed as a candidate for probing physics beyond the Standard Model of particle physics. Since studies with $^{229}$PaF$^{3+}$ require significant experimental advances, we exploit the stable, valence-isoelectronic dicationic cerium monofluoride (CeF$^{2+}$) as a surrogate. Gas-phase fluorinated-cerium molecular ions are formed and identified using the Off-Line Ion Source and TITAN mass measurement facilities at TRIUMF. Quantum chemical calculations are performed on the electronic structure of CeF$^{2+}$, revealing a parallel to that of $^{229}$PaF$^{3+}$. Moreover, these calculations provide estimates on the sensitivity of CeF$^{2+}$ itself to various $\mathcal{P,T}$-odd properties. A brief discourse on the specifics of the quantum control of CeF$^{2+}$ is presented which anticipates future searches for symmetry violations.
title Formation of gaseous, doubly charged cerium monofluoride CeF$^{2+}$ and its sensitivity to new physics
topic Atomic Physics
Nuclear Experiment
Nuclear Theory
Quantum Physics
url https://arxiv.org/abs/2604.26109