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| Autori principali: | , , , , |
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| Natura: | Preprint |
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2026
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| Accesso online: | https://arxiv.org/abs/2605.00304 |
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| _version_ | 1866914524111568896 |
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| author | Nozawa, Koki Saitoh, Noriyuki Yoshizawa, Noriko Suemasu, Takashi Toko, Kaoru |
| author_facet | Nozawa, Koki Saitoh, Noriyuki Yoshizawa, Noriko Suemasu, Takashi Toko, Kaoru |
| contents | Achieving long-term stability in high-capacity lithium-ion battery anodes remains a critical challenge. In this study, we present a materials-intrinsic strategy for extending the cycle life of Ge, a promising next-generation anode material, through trace doping with metal elements. We systematically investigated the effects of small additions of various metals and found that elements with large atomic size, particularly Yb, markedly improved the cycling stability without sacrificing the initial capacity, while appropriate Yb doping enhanced the anode lifetime by approximately a factor of three. Structural and electrochemical analyses revealed that this improvement originates from mechanical softening of the Ge anode, which suppresses lithiation-induced damage such as cracking and delamination. Nanoindentation measurements further showed a strong negative correlation between dopant atomic size and film hardness, establishing anode softening as a new design principle for damage-tolerant electrodes. Although Yb doping reduced the rate capability at high C-rates, the present results demonstrate a clear shift in design strategy from volume-change suppression to mechanical compliance. These findings provide a useful framework for stabilizing high-capacity alloy anodes through atomic-scale mechanical control. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2605_00304 |
| institution | arXiv |
| publishDate | 2026 |
| record_format | arxiv |
| spellingShingle | Tailoring Mechanical Properties of Germanium Anodes via Metal Incorporation for Improved Cycle Stability Nozawa, Koki Saitoh, Noriyuki Yoshizawa, Noriko Suemasu, Takashi Toko, Kaoru Materials Science Applied Physics Achieving long-term stability in high-capacity lithium-ion battery anodes remains a critical challenge. In this study, we present a materials-intrinsic strategy for extending the cycle life of Ge, a promising next-generation anode material, through trace doping with metal elements. We systematically investigated the effects of small additions of various metals and found that elements with large atomic size, particularly Yb, markedly improved the cycling stability without sacrificing the initial capacity, while appropriate Yb doping enhanced the anode lifetime by approximately a factor of three. Structural and electrochemical analyses revealed that this improvement originates from mechanical softening of the Ge anode, which suppresses lithiation-induced damage such as cracking and delamination. Nanoindentation measurements further showed a strong negative correlation between dopant atomic size and film hardness, establishing anode softening as a new design principle for damage-tolerant electrodes. Although Yb doping reduced the rate capability at high C-rates, the present results demonstrate a clear shift in design strategy from volume-change suppression to mechanical compliance. These findings provide a useful framework for stabilizing high-capacity alloy anodes through atomic-scale mechanical control. |
| title | Tailoring Mechanical Properties of Germanium Anodes via Metal Incorporation for Improved Cycle Stability |
| topic | Materials Science Applied Physics |
| url | https://arxiv.org/abs/2605.00304 |