Origin and evolution of NiI and FeI in the coma of the interstellar comet 3I/ATLAS throughout its trajectory

Fuente: arXiv
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Auteurs principaux: Hutsemékers, Damien, Manfroid, Jean, Opitom, Cyrielle, Jehin, Emmanuël, Krishnakumar, Aravind, Fernandes, Fernando Massa, Bannister, Michele, Bodewits, Dennis, Dorsey, Rosemary, La Forgia, Fiorangela, Murphy, Brian
Format: Preprint
Publié: 2026
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author Hutsemékers, Damien
Manfroid, Jean
Opitom, Cyrielle
Jehin, Emmanuël
Krishnakumar, Aravind
Fernandes, Fernando Massa
Bannister, Michele
Bodewits, Dennis
Dorsey, Rosemary
La Forgia, Fiorangela
Murphy, Brian
author_facet Hutsemékers, Damien
Manfroid, Jean
Opitom, Cyrielle
Jehin, Emmanuël
Krishnakumar, Aravind
Fernandes, Fernando Massa
Bannister, Michele
Bodewits, Dennis
Dorsey, Rosemary
La Forgia, Fiorangela
Murphy, Brian
contents We present high-resolution UVES+VLT observations of neutral nickel and iron atoms in the coma of the interstellar comet 3I/ATLAS taken after perihelion. Metal emission was strong shortly after perihelion and persisted at large heliocentric distances. At $r_h \sim 2$ au the total metal production rate was found to be at least an order of magnitude larger than that of typical solar-system comets. Post-perihelion production rates exhibit pronounced asymmetry compared to the pre-perihelion behavior: production rates are higher after perihelion and decline more gradually with $r_h$, the difference being stronger for FeI. The NiI/FeI abundance ratio, initially anomalously large before perihelion, evolved toward values comparable to solar-system comets near 2 au, and shows a weaker $r_h$ dependence after perihelion. To interpret these results, we revisited and extended the carbonyl hypothesis in which FeI and NiI are produced by the rapid photodissociation of Fe(CO)$_5$ and Ni(CO)$_4$ vaporized from the nucleus. Fits that include direct sublimation of carbonyls reproduce the observed rates and the high NiI/FeI line ratio, which is determined by the higher volatility of Ni(CO)$_4$. Desorption of carbonyls from sublimating CO$_2$ and H$_2$O ices is found to be negligible. The temperature profiles needed to reproduce the observations were found to be shallower than the equilibrium $T \propto r_h^{-1/2}$ relation, suggesting that the sublimation could occur below the surface of the nucleus. Fits using temperature profiles from thermal models require sublimation from depths of several cm, especially post-perihelion. An additional transient heat source ($T \simeq$ 100-140~K), possibly linked to the amorphous-crystalline ice transition, is proposed to explain the early NiI excess before perihelion.
format Preprint
id arxiv_https___arxiv_org_abs_2605_07652
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Origin and evolution of NiI and FeI in the coma of the interstellar comet 3I/ATLAS throughout its trajectory
Hutsemékers, Damien
Manfroid, Jean
Opitom, Cyrielle
Jehin, Emmanuël
Krishnakumar, Aravind
Fernandes, Fernando Massa
Bannister, Michele
Bodewits, Dennis
Dorsey, Rosemary
La Forgia, Fiorangela
Murphy, Brian
Earth and Planetary Astrophysics
Astrophysics of Galaxies
We present high-resolution UVES+VLT observations of neutral nickel and iron atoms in the coma of the interstellar comet 3I/ATLAS taken after perihelion. Metal emission was strong shortly after perihelion and persisted at large heliocentric distances. At $r_h \sim 2$ au the total metal production rate was found to be at least an order of magnitude larger than that of typical solar-system comets. Post-perihelion production rates exhibit pronounced asymmetry compared to the pre-perihelion behavior: production rates are higher after perihelion and decline more gradually with $r_h$, the difference being stronger for FeI. The NiI/FeI abundance ratio, initially anomalously large before perihelion, evolved toward values comparable to solar-system comets near 2 au, and shows a weaker $r_h$ dependence after perihelion. To interpret these results, we revisited and extended the carbonyl hypothesis in which FeI and NiI are produced by the rapid photodissociation of Fe(CO)$_5$ and Ni(CO)$_4$ vaporized from the nucleus. Fits that include direct sublimation of carbonyls reproduce the observed rates and the high NiI/FeI line ratio, which is determined by the higher volatility of Ni(CO)$_4$. Desorption of carbonyls from sublimating CO$_2$ and H$_2$O ices is found to be negligible. The temperature profiles needed to reproduce the observations were found to be shallower than the equilibrium $T \propto r_h^{-1/2}$ relation, suggesting that the sublimation could occur below the surface of the nucleus. Fits using temperature profiles from thermal models require sublimation from depths of several cm, especially post-perihelion. An additional transient heat source ($T \simeq$ 100-140~K), possibly linked to the amorphous-crystalline ice transition, is proposed to explain the early NiI excess before perihelion.
title Origin and evolution of NiI and FeI in the coma of the interstellar comet 3I/ATLAS throughout its trajectory
topic Earth and Planetary Astrophysics
Astrophysics of Galaxies
url https://arxiv.org/abs/2605.07652