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| Format: | Preprint |
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2026
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| Online Access: | https://arxiv.org/abs/2605.10252 |
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| _version_ | 1866910208041680896 |
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| author | Bae, Changdeuck |
| author_facet | Bae, Changdeuck |
| contents | We propose a minimal nonlinear closure ODE for the dynamic active-area factor of a battery interface and show that it exhibits a saddle-node bifurcation when the smoothing rate saturates with surface roughness. The closure is the simplest physically motivated extension of a recently introduced single-fixed-point closure [C. Bae, in preparation (2026)]: u = K - u/(1 + alphau^2), where u = xi - 1 is the dimensionless excess active area, K the dimensionless drive, and alpha a single saturation parameter. The bifurcation occurs at K_c = 1/(2sqrt(alpha)), separating a smooth passivating phase from a morphologically unstable phase. Mapping four canonical anode configurations -- graphite, silicon composite, lithium metal, and anode-free Li/Cu -- onto the closure via end-of-cycling steady-state xi extracted from publicly available long-cycle data populates the stable branch with monotonically increasing K/K_c ratios: graphite (~0.01), silicon composite (~0.24), lithium metal (~0.73), and anode-free (~0.95). The anode-free configuration sits within 5% of the saddle-node threshold, predicting a vanishingly small operational stability window in current density, temperature, and electrolyte composition. We test three falsifiable predictions of the framework -- a critical current density, a critical temperature shift, and a mean-field critical-slowing-down exponent -- and find them broadly consistent with publicly available data. We argue that this near-critical position is universal to nucleation-controlled deposition on non-passivating substrates. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2605_10252 |
| institution | arXiv |
| publishDate | 2026 |
| record_format | arxiv |
| spellingShingle | Saddle-node bifurcation in interfacial morphology selects battery degradation phase Bae, Changdeuck Materials Science We propose a minimal nonlinear closure ODE for the dynamic active-area factor of a battery interface and show that it exhibits a saddle-node bifurcation when the smoothing rate saturates with surface roughness. The closure is the simplest physically motivated extension of a recently introduced single-fixed-point closure [C. Bae, in preparation (2026)]: u = K - u/(1 + alphau^2), where u = xi - 1 is the dimensionless excess active area, K the dimensionless drive, and alpha a single saturation parameter. The bifurcation occurs at K_c = 1/(2sqrt(alpha)), separating a smooth passivating phase from a morphologically unstable phase. Mapping four canonical anode configurations -- graphite, silicon composite, lithium metal, and anode-free Li/Cu -- onto the closure via end-of-cycling steady-state xi extracted from publicly available long-cycle data populates the stable branch with monotonically increasing K/K_c ratios: graphite (~0.01), silicon composite (~0.24), lithium metal (~0.73), and anode-free (~0.95). The anode-free configuration sits within 5% of the saddle-node threshold, predicting a vanishingly small operational stability window in current density, temperature, and electrolyte composition. We test three falsifiable predictions of the framework -- a critical current density, a critical temperature shift, and a mean-field critical-slowing-down exponent -- and find them broadly consistent with publicly available data. We argue that this near-critical position is universal to nucleation-controlled deposition on non-passivating substrates. |
| title | Saddle-node bifurcation in interfacial morphology selects battery degradation phase |
| topic | Materials Science |
| url | https://arxiv.org/abs/2605.10252 |