Helium Bubbles in Liquid Lead Lithium Solutions: Pressure Inhomogeneities at Interfaces and Non Ideal Mixture Effects

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Autori principali: Alvarez-Galera, Edgar, Marti, Jordi, Batet, Lluis
Natura: Preprint
Pubblicazione: 2026
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author Alvarez-Galera, Edgar
Marti, Jordi
Batet, Lluis
author_facet Alvarez-Galera, Edgar
Marti, Jordi
Batet, Lluis
contents The extremely low solubility of helium in liquid metals may lead to rapid supersaturation, promoting spontaneous formation of helium bubbles by nucleation. Once nucleated, the stability of these bubbles is governed by the properties of the helium liquid metal interface. In particular, interfacial tension between the immiscible phases controls bubble interactions and induces local pressure inhomogeneities. This work is motivated by the need of a better understanding of helium bubble formation in liquid Pb Li alloys, which are of particular relevance for the design of breeding blankets in the future nuclear fusion reactors. We employ classical molecular dynamics simulations to investigate helium segregation in a range of lead lithium systems, including the limiting cases of pure lead and pure lithium. Changes in local pressure are evaluated from direct mechanical calculations, enabling the characterization of interfacial properties. Interfacial tension and radius of the bubble are subsequently determined across multiple thermodynamic conditions, spanning temperatures starting near the melting points of the constituent metals up to 1021 K. The impact of curvature and composition of the alloy on the interfacial behaviour are also investigated.
format Preprint
id arxiv_https___arxiv_org_abs_2605_13164
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Helium Bubbles in Liquid Lead Lithium Solutions: Pressure Inhomogeneities at Interfaces and Non Ideal Mixture Effects
Alvarez-Galera, Edgar
Marti, Jordi
Batet, Lluis
Materials Science
Chemical Physics
The extremely low solubility of helium in liquid metals may lead to rapid supersaturation, promoting spontaneous formation of helium bubbles by nucleation. Once nucleated, the stability of these bubbles is governed by the properties of the helium liquid metal interface. In particular, interfacial tension between the immiscible phases controls bubble interactions and induces local pressure inhomogeneities. This work is motivated by the need of a better understanding of helium bubble formation in liquid Pb Li alloys, which are of particular relevance for the design of breeding blankets in the future nuclear fusion reactors. We employ classical molecular dynamics simulations to investigate helium segregation in a range of lead lithium systems, including the limiting cases of pure lead and pure lithium. Changes in local pressure are evaluated from direct mechanical calculations, enabling the characterization of interfacial properties. Interfacial tension and radius of the bubble are subsequently determined across multiple thermodynamic conditions, spanning temperatures starting near the melting points of the constituent metals up to 1021 K. The impact of curvature and composition of the alloy on the interfacial behaviour are also investigated.
title Helium Bubbles in Liquid Lead Lithium Solutions: Pressure Inhomogeneities at Interfaces and Non Ideal Mixture Effects
topic Materials Science
Chemical Physics
url https://arxiv.org/abs/2605.13164