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Bibliographic Details
Main Authors: Harwood, Anthony C, Lim, Sean Z J, Raziman, T V, Li, Yan, Stones, Joseph, Tisch, John W G, Horsley, Simon A R, Vezzoli, Stefano, Pendry, John B, Sapienza, Riccardo
Format: Preprint
Published: 2026
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Online Access:https://arxiv.org/abs/2605.21432
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author Harwood, Anthony C
Lim, Sean Z J
Raziman, T V
Li, Yan
Stones, Joseph
Tisch, John W G
Horsley, Simon A R
Vezzoli, Stefano
Pendry, John B
Sapienza, Riccardo
author_facet Harwood, Anthony C
Lim, Sean Z J
Raziman, T V
Li, Yan
Stones, Joseph
Tisch, John W G
Horsley, Simon A R
Vezzoli, Stefano
Pendry, John B
Sapienza, Riccardo
contents Transparent conducting oxides near their epsilon-near-zero frequency exhibit near-unity ultrafast modulations of the refractive index which have enabled the field of time-varying metamaterials, yet the underlying carrier dynamics at high driving fluences remain poorly understood. Here, we report ultrafast modulations in the reflectivity and transmissivity of indium tin oxide, and a non-monotonic oscillatory behavior. This is especially evident in the time evolution of the complex Fresnel coefficients retrieved directly from pump-probe spectrograms using a optical gating technique, GRUMPY FROG. The dynamics of the retrieved plasma frequency and damping coefficient are well captured by an extended two-temperature model incorporating a competing nonlinear interband process: at high fluences, Auger-type scattering of hot conduction electrons promotes valence band carriers, increasing the plasma frequency while accelerating hot-electron cooling and raising the damping coefficient. These results clarify the origin of anomalous high-fluence dynamics in indium tin oxide and identify a fluence-tuneable modulation dynamic with direct implications for ultrafast refractive index engineering in time-varying photonic devices and optical switching
format Preprint
id arxiv_https___arxiv_org_abs_2605_21432
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Intraband and Interband Competition Drives Ultrafast Modulations of Indium Tin Oxide
Harwood, Anthony C
Lim, Sean Z J
Raziman, T V
Li, Yan
Stones, Joseph
Tisch, John W G
Horsley, Simon A R
Vezzoli, Stefano
Pendry, John B
Sapienza, Riccardo
Optics
Transparent conducting oxides near their epsilon-near-zero frequency exhibit near-unity ultrafast modulations of the refractive index which have enabled the field of time-varying metamaterials, yet the underlying carrier dynamics at high driving fluences remain poorly understood. Here, we report ultrafast modulations in the reflectivity and transmissivity of indium tin oxide, and a non-monotonic oscillatory behavior. This is especially evident in the time evolution of the complex Fresnel coefficients retrieved directly from pump-probe spectrograms using a optical gating technique, GRUMPY FROG. The dynamics of the retrieved plasma frequency and damping coefficient are well captured by an extended two-temperature model incorporating a competing nonlinear interband process: at high fluences, Auger-type scattering of hot conduction electrons promotes valence band carriers, increasing the plasma frequency while accelerating hot-electron cooling and raising the damping coefficient. These results clarify the origin of anomalous high-fluence dynamics in indium tin oxide and identify a fluence-tuneable modulation dynamic with direct implications for ultrafast refractive index engineering in time-varying photonic devices and optical switching
title Intraband and Interband Competition Drives Ultrafast Modulations of Indium Tin Oxide
topic Optics
url https://arxiv.org/abs/2605.21432