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Autori principali: Park, Sungwan, Choi, Justin Jeongwoo, Liu, Albert Tianxiang
Natura: Preprint
Pubblicazione: 2026
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Accesso online:https://arxiv.org/abs/2605.27251
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author Park, Sungwan
Choi, Justin Jeongwoo
Liu, Albert Tianxiang
author_facet Park, Sungwan
Choi, Justin Jeongwoo
Liu, Albert Tianxiang
contents Capillarity-driven self-assembly at fluidic interfaces offers a scalable route to large, reconfigurable materials. Microscale particles with high horizontal-to-vertical aspect ratios become attractive building blocks for shape-directed organization, but the capillary rules governing their assembly remain incompletely understood. Here, we combine experiments and theory to explain the transition between two capillary regimes: monopolar interactions arising from millimeter-scale curved interfaces, and quadrupolar interactions arising from local contact-line distortions. We show that the conventional Bond number is insufficient to predict this transition because it omits key material and surface-topography effects. Instead, we identify a new dimensionless parameter that captures the coupled roles of particle size, density, surface roughness, contact angle, and quadrupolar strength. This criterion correctly predicts when gravitationally induced monopolar attraction or surface-pinning-induced quadrupolar attraction dominates, providing a general design rule for interfacial particle assembly. The resulting model explains how particles self-organize across length scales and offers guiding principles for engineering next-generation interfacial materials from miniaturized particulate building blocks.
format Preprint
id arxiv_https___arxiv_org_abs_2605_27251
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Resolving Capillary Mode Transitions in Microparticles at Fluid Interfaces
Park, Sungwan
Choi, Justin Jeongwoo
Liu, Albert Tianxiang
Soft Condensed Matter
Capillarity-driven self-assembly at fluidic interfaces offers a scalable route to large, reconfigurable materials. Microscale particles with high horizontal-to-vertical aspect ratios become attractive building blocks for shape-directed organization, but the capillary rules governing their assembly remain incompletely understood. Here, we combine experiments and theory to explain the transition between two capillary regimes: monopolar interactions arising from millimeter-scale curved interfaces, and quadrupolar interactions arising from local contact-line distortions. We show that the conventional Bond number is insufficient to predict this transition because it omits key material and surface-topography effects. Instead, we identify a new dimensionless parameter that captures the coupled roles of particle size, density, surface roughness, contact angle, and quadrupolar strength. This criterion correctly predicts when gravitationally induced monopolar attraction or surface-pinning-induced quadrupolar attraction dominates, providing a general design rule for interfacial particle assembly. The resulting model explains how particles self-organize across length scales and offers guiding principles for engineering next-generation interfacial materials from miniaturized particulate building blocks.
title Resolving Capillary Mode Transitions in Microparticles at Fluid Interfaces
topic Soft Condensed Matter
url https://arxiv.org/abs/2605.27251