Topological Edge States from Molecular Chirality: A General Framework for Dimerized Dipolar Arrays

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Main Authors: Akbar, Muhammad Arsalan Ali, Raza, Mohsin, Kais, Sabre
Format: Preprint
Published: 2026
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author Akbar, Muhammad Arsalan Ali
Raza, Mohsin
Kais, Sabre
author_facet Akbar, Muhammad Arsalan Ali
Raza, Mohsin
Kais, Sabre
contents We establish a general theoretical framework for realizing topological edge states in dimerized arrays of chiral dipolar molecules and demonstrate that molecular handedness provides a natural and tunable route to SSH-like topology in an interacting one-dimensional setting. Starting from an effective spin-$\tfrac{1}{2}$ model generated by Stark-dressed chiral molecules, we introduce bond dimerization and show that the chirality-induced Dzyaloshinskii--Moriya interaction amplifies the effective hopping amplitudes and enlarges the bulk topological gap relative to an achiral chain of equivalent dipole strength. Using self-consistent mean-field theory with periodic- and open-boundary calculations, we map out the trivial, critical, and topological regimes through bulk spectra, complex-plane winding, and boundary-localized probability densities. A central result is that the two in-gap boundary modes carry \emph{opposite molecular chirality}: the left edge state localizes on a left-handed molecule and the right edge state on a right-handed molecule, a stereochemical labeling with no analogue in conventional SSH implementations. The two-leg ladder extension supports a richer four-band bulk structure and a rung-split edge sector whose robustness is characterized by a continuous sweep of the interchain coupling. All results are expressed in dimensionless units of the reference hopping scale $t_0$, making the framework directly applicable to any dipolar molecular platform -- from bialkali polar molecules at MHz coupling scales to future arrays of ultracold chiral polyatomic species. These findings establish dimerized chiral molecular arrays as a controllable and chirality-addressable platform for quasi-one-dimensional topological quantum matter.
format Preprint
id arxiv_https___arxiv_org_abs_2606_00877
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Topological Edge States from Molecular Chirality: A General Framework for Dimerized Dipolar Arrays
Akbar, Muhammad Arsalan Ali
Raza, Mohsin
Kais, Sabre
Quantum Physics
Materials Science
Applied Physics
Atomic and Molecular Clusters
We establish a general theoretical framework for realizing topological edge states in dimerized arrays of chiral dipolar molecules and demonstrate that molecular handedness provides a natural and tunable route to SSH-like topology in an interacting one-dimensional setting. Starting from an effective spin-$\tfrac{1}{2}$ model generated by Stark-dressed chiral molecules, we introduce bond dimerization and show that the chirality-induced Dzyaloshinskii--Moriya interaction amplifies the effective hopping amplitudes and enlarges the bulk topological gap relative to an achiral chain of equivalent dipole strength. Using self-consistent mean-field theory with periodic- and open-boundary calculations, we map out the trivial, critical, and topological regimes through bulk spectra, complex-plane winding, and boundary-localized probability densities. A central result is that the two in-gap boundary modes carry \emph{opposite molecular chirality}: the left edge state localizes on a left-handed molecule and the right edge state on a right-handed molecule, a stereochemical labeling with no analogue in conventional SSH implementations. The two-leg ladder extension supports a richer four-band bulk structure and a rung-split edge sector whose robustness is characterized by a continuous sweep of the interchain coupling. All results are expressed in dimensionless units of the reference hopping scale $t_0$, making the framework directly applicable to any dipolar molecular platform -- from bialkali polar molecules at MHz coupling scales to future arrays of ultracold chiral polyatomic species. These findings establish dimerized chiral molecular arrays as a controllable and chirality-addressable platform for quasi-one-dimensional topological quantum matter.
title Topological Edge States from Molecular Chirality: A General Framework for Dimerized Dipolar Arrays
topic Quantum Physics
Materials Science
Applied Physics
Atomic and Molecular Clusters
url https://arxiv.org/abs/2606.00877