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| Main Authors: | , , , |
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| Format: | Preprint |
| Published: |
2026
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| Subjects: | |
| Online Access: | https://arxiv.org/abs/2606.02466 |
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Table of Contents:
- In this report we demonstrate dense polycrystalline calcium hydroxide ceramics fabricated by hydrothermally-assisted sintering - often referred to as cold-sintering - to produce high-purity calcium hydroxide targets for calcium oxide thin film deposition. Calcium hydroxide ceramics exhibit up to 98% theoretical density without thermal dehydration, when sintered at temperatures between 100 °C - 300° C with 400 MPa applied uniaxial pressure for 1 hour. The brucite phase is preserved in calcium hydroxide targets at all temperatures. Small equivalent fractions of calcium carbonate are present in both the calcium hydroxide precursor powder and final targets suggesting minimal additional production during formation and densification. Microstructure evolution during densification is documented by scanning electron microscopy, indicating both mass transport and plastic deformation densification mechanisms. The hydrothermal-assisted sintering process is scaled up to produce 2-inch diameter calcium hydroxide targets suitable for sputter deposition. We also report epitaxial calcium oxide film deposition from these targets on r-plane sapphire substrates. (002) oriented epitaxial films are achieved with a time-stable 1.2 nm per minute deposition rate. We note that energetic bombardment during growth can be substantial at these rates even when 1 mol% oxygen is added to the sputtering process necessitating the low deposition rate conditions.