A Wet-Lab Approach to Stereochemistry Using [superscript 31]P NMR Spectroscopy

Fuente: ERIC Institute of Education Sciences

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Bibliographic Details
Main Authors:	Fenton, Owen S., Sculimbrene, Bianca R.
Format:	Recurso educativo Open Access
Language:	en
Published:	2011
Subjects:	Organic Chemistry Spectroscopy College Science Scientific Concepts Molecular Structure Science Experiments Scientific Principles Science Laboratories
Online Access:	Acceder al recurso
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author	Fenton, Owen S. Sculimbrene, Bianca R.
author_facet	Fenton, Owen S. Sculimbrene, Bianca R. Fenton, Owen S. Sculimbrene, Bianca R.
collection	Education Resources Information Center
contents	A Wet-Lab Approach to Stereochemistry Using [superscript 31]P NMR Spectroscopy Fenton, Owen S. Sculimbrene, Bianca R. Organic Chemistry Spectroscopy College Science Scientific Concepts Molecular Structure Science Experiments Scientific Principles Science Laboratories Understanding stereochemistry is an important and difficult task for students to master in organic chemistry. In both introductory and advanced courses, students are encouraged to explore the spatial relationships between molecules, but this exploration is often limited either to the lecture hall or the confines of the library. As such, we sought to develop an experiment-based approach that would facilitate investigation of stereochemical principles in an organic chemistry laboratory. Herein is reported a [superscript 31]P NMR-based experiment that allows students to explore the different stereochemical outcomes when enantiopure or racemic alcohols are coupled to an achiral phosphorous center. (Contains 1 figure and 2 schemes.)
format	Recurso educativo Open Access
id	eric_EJ936779
institution	ERIC Institute of Education Sciences
language	en
publishDate	2011
record_format	eric
spellingShingle	A Wet-Lab Approach to Stereochemistry Using [superscript 31]P NMR Spectroscopy Fenton, Owen S. Sculimbrene, Bianca R. Organic Chemistry Spectroscopy College Science Scientific Concepts Molecular Structure Science Experiments Scientific Principles Science Laboratories A Wet-Lab Approach to Stereochemistry Using [superscript 31]P NMR Spectroscopy Fenton, Owen S. Sculimbrene, Bianca R. Organic Chemistry Spectroscopy College Science Scientific Concepts Molecular Structure Science Experiments Scientific Principles Science Laboratories Understanding stereochemistry is an important and difficult task for students to master in organic chemistry. In both introductory and advanced courses, students are encouraged to explore the spatial relationships between molecules, but this exploration is often limited either to the lecture hall or the confines of the library. As such, we sought to develop an experiment-based approach that would facilitate investigation of stereochemical principles in an organic chemistry laboratory. Herein is reported a [superscript 31]P NMR-based experiment that allows students to explore the different stereochemical outcomes when enantiopure or racemic alcohols are coupled to an achiral phosphorous center. (Contains 1 figure and 2 schemes.)
title	A Wet-Lab Approach to Stereochemistry Using [superscript 31]P NMR Spectroscopy
topic	Organic Chemistry Spectroscopy College Science Scientific Concepts Molecular Structure Science Experiments Scientific Principles Science Laboratories
url	https://eric.ed.gov/?id=EJ936779

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