Chemical composition and isotope ratios of basalts from DSDP Sites 417 and 418, West Atlantic Ocean

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Autores principales: Staudigel, Hubert, Frey, Frederick A, Hart, Stanley R
Formato: Dataset Open Access
Lenguaje:en
Publicado: PANGAEA 1979
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author Staudigel, Hubert
Frey, Frederick A
Hart, Stanley R
author_facet Staudigel, Hubert
Frey, Frederick A
Hart, Stanley R
collection Datos científicos de ciencias marinas y ambientales
contents Basalts from Sites 417 and 418 are relatively depleted in light REE compared to a chondritic REE distribution. In the least altered samples, K, Rb, Cs, and Sr and Ba concentrations are lower than in average mid-ocean ridge basalt (MORB). Thus, the source rock for these basalts must have been highly depleted in incompatible elements. However, 87/86Sr ratios in these basalts, even in microscopically fresh glass, are high (> 0.7030). These ratios, compared to normal MORB, are largely an effect of low-temperature alteration. Sr isotope exchange with sea water is postulated for basaltic glass (87/86Sr = 0.70301) with low incompatible-element abundances, but we cannot eliminate the possibility that these relatively high 87/86Sr ratios are primary. By studying closely associated glass-palagonite-crystalline rock samples, we can identify two types of alteration processes: (1) palagonite formation which causes loss of REE elements, without changing their distribution, and decreasing K/Rb and K/Cs with increasing K content; and (2) glass-sea water exchange which is apparently a diffusioncontrolled process, causing increasing K/Rb and K/Cs with increasing K content but not affecting REE.
format Dataset Open Access
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institution PANGAEA
language en
publishDate 1979
publisher PANGAEA
record_format pangaea
spellingShingle Chemical composition and isotope ratios of basalts from DSDP Sites 417 and 418, West Atlantic Ocean
Staudigel, Hubert
Frey, Frederick A
Hart, Stanley R
51-417D; 52-417D; 52-418A; 53-418A; Deep Sea Drilling Project; DRILL; Drilling/drill rig; DSDP; Glomar Challenger; Leg51; Leg52; Leg53; North Atlantic/CONT RISE
Basalts from Sites 417 and 418 are relatively depleted in light REE compared to a chondritic REE distribution. In the least altered samples, K, Rb, Cs, and Sr and Ba concentrations are lower than in average mid-ocean ridge basalt (MORB). Thus, the source rock for these basalts must have been highly depleted in incompatible elements. However, 87/86Sr ratios in these basalts, even in microscopically fresh glass, are high (> 0.7030). These ratios, compared to normal MORB, are largely an effect of low-temperature alteration. Sr isotope exchange with sea water is postulated for basaltic glass (87/86Sr = 0.70301) with low incompatible-element abundances, but we cannot eliminate the possibility that these relatively high 87/86Sr ratios are primary. By studying closely associated glass-palagonite-crystalline rock samples, we can identify two types of alteration processes: (1) palagonite formation which causes loss of REE elements, without changing their distribution, and decreasing K/Rb and K/Cs with increasing K content; and (2) glass-sea water exchange which is apparently a diffusioncontrolled process, causing increasing K/Rb and K/Cs with increasing K content but not affecting REE.
title Chemical composition and isotope ratios of basalts from DSDP Sites 417 and 418, West Atlantic Ocean
topic 51-417D; 52-417D; 52-418A; 53-418A; Deep Sea Drilling Project; DRILL; Drilling/drill rig; DSDP; Glomar Challenger; Leg51; Leg52; Leg53; North Atlantic/CONT RISE
url https://doi.org/10.1594/PANGAEA.667438