Organic δ¹³C values, kerogen atomic C/N ratios and relative weights of some kerogen pyrolysis products of ODP Hole 112-682A (Table 1)

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Autores principales: Vetó, István, Hertelendi, Ede, Sajgó, Csanád, Brukner-Wein, Alice
Formato: Dataset Open Access
Lenguaje:en
Publicado: PANGAEA 1999
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author Vetó, István
Hertelendi, Ede
Sajgó, Csanád
Brukner-Wein, Alice
author_facet Vetó, István
Hertelendi, Ede
Sajgó, Csanád
Brukner-Wein, Alice
collection Datos científicos de ciencias marinas y ambientales
contents Carbon isotopic composition of predominantly marine kerogen in latest Oligocene mudstones of the Peru Margin ODP 682A Hole shows an about 3.5 per mil increase with decreasing age. Py-GC and elemental (C=N ratio) analysis of the kerogen plus sulphur isotopic study together with earlier knowledge on geological setting and organic geochemistry results in a better understanding of depositionary environment and allows to separation of the influence of concentration of water dissolved carbon dioxide (ce) on kerogen delta13C from that of other factors (bacterial degradation, sea surface temperature, DIC delta13C, productivity, and admixture of land plant OM). Based on this analysis, the major part of the kerogen shift is considered as a result of the latest Oligocene decrease of marine photosynthetic carbon isotopic fractionation in the Peru Margin photic zone, which in turn possibly reflects a simultaneous drop in atmospheric CO2 level. Uncertainties in the evaluation of the factors affecting the marine photosynthetic carbon isotopic fractionation and the extent of ocean-atmosphere disequilibrium do not permit calculation of the decrease of the atmospheric CO2.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_704907
institution PANGAEA
language en
publishDate 1999
publisher PANGAEA
record_format pangaea
spellingShingle Organic δ¹³C values, kerogen atomic C/N ratios and relative weights of some kerogen pyrolysis products of ODP Hole 112-682A (Table 1)
Vetó, István
Hertelendi, Ede
Sajgó, Csanád
Brukner-Wein, Alice
112-682A; Carbon/Nitrogen ratio; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Element analyser, Fisons NA 1500 NCS; Epoch; Isotope ratio mass spectrometry; Joides Resolution; Leg112; Meta- and paraxylene; n-octene; Ocean Drilling Program; ODP; Phenols; Sample code/label; South Pacific Ocean; δ13C
Carbon isotopic composition of predominantly marine kerogen in latest Oligocene mudstones of the Peru Margin ODP 682A Hole shows an about 3.5 per mil increase with decreasing age. Py-GC and elemental (C=N ratio) analysis of the kerogen plus sulphur isotopic study together with earlier knowledge on geological setting and organic geochemistry results in a better understanding of depositionary environment and allows to separation of the influence of concentration of water dissolved carbon dioxide (ce) on kerogen delta13C from that of other factors (bacterial degradation, sea surface temperature, DIC delta13C, productivity, and admixture of land plant OM). Based on this analysis, the major part of the kerogen shift is considered as a result of the latest Oligocene decrease of marine photosynthetic carbon isotopic fractionation in the Peru Margin photic zone, which in turn possibly reflects a simultaneous drop in atmospheric CO2 level. Uncertainties in the evaluation of the factors affecting the marine photosynthetic carbon isotopic fractionation and the extent of ocean-atmosphere disequilibrium do not permit calculation of the decrease of the atmospheric CO2.
title Organic δ¹³C values, kerogen atomic C/N ratios and relative weights of some kerogen pyrolysis products of ODP Hole 112-682A (Table 1)
topic 112-682A; Carbon/Nitrogen ratio; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Element analyser, Fisons NA 1500 NCS; Epoch; Isotope ratio mass spectrometry; Joides Resolution; Leg112; Meta- and paraxylene; n-octene; Ocean Drilling Program; ODP; Phenols; Sample code/label; South Pacific Ocean; δ13C
url https://doi.org/10.1594/PANGAEA.704907